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Geometry for Si(CH3)4 (tetramethylsilane) 1A1 TD

1910171554
InChI=1S/C4H12Si/c1-5(2,3)4/h1-4H3 INChIKey=CZDYPVPMEAXLPK-UHFFFAOYSA-N

HF/TZVP


Point group is Td
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
C2 1.0949 1.0949 1.0949   1.6219 0.9819 0.0438
C3 -1.0949 -1.0949 1.0949   0.3858 -1.8563 -0.0438
C4 -1.0949 1.0949 -1.0949   -1.0213 0.3971 1.5478
C5 1.0949 -1.0949 -1.0949   -0.9864 0.4773 -1.5478
H6 1.7351 0.4946 1.7351   2.2300 0.7749 -0.8322
H7 1.7351 1.7351 0.4946   1.4329 2.0513 0.0694
H8 0.4946 1.7351 1.7351   2.2102 0.7294 0.9214
H9 -1.7351 -1.7351 0.4946   -0.5259 -2.4463 -0.0694
H10 -0.4946 -1.7351 1.7351   0.9714 -2.1150 -0.9214
H11 -1.7351 -0.4946 1.7351   0.9516 -2.1605 0.8322
H12 -1.7351 0.4946 -1.7351   -1.9587 -0.1519 1.5512
H13 -1.7351 1.7351 -0.4946   -0.4812 0.1339 2.4528
H14 -0.4946 1.7351 -1.7351   -1.2585 1.4558 1.6008
H15 1.7351 -1.7351 -0.4946   -0.4258 0.2611 -2.4528
H16 0.4946 -1.7351 -1.7351   -1.9231 -0.0702 -1.6008
H17 1.7351 -0.4946 -1.7351   -1.2229 1.5375 -1.5512
Atom - Atom Distances (Å)
  Si1 C2 C3 C4 C5 H6 H7 H8 H9 H10 H11 H12 H13 H14 H15 H16 H17
Si1 1.8965 1.8965 1.8965 1.8965 2.5031 2.5031 2.5031 2.5031 2.5031 2.5031 2.5031 2.5031 2.5031 2.5031 2.5031 2.5031
C2 1.8965 3.0969 3.0969 3.0969 1.0863 1.0863 1.0863 4.0470 3.3084 3.3084 4.0470 3.3084 3.3084 3.3084 4.0470 3.3084
C3 1.8965 3.0969 3.0969 3.0969 3.3084 4.0470 3.3084 1.0863 1.0863 1.0863 3.3084 3.3084 4.0470 3.3084 3.3084 4.0470
C4 1.8965 3.0969 3.0969 3.0969 4.0470 3.3084 3.3084 3.3084 4.0470 3.3084 1.0863 1.0863 1.0863 4.0470 3.3084 3.3084
C5 1.8965 3.0969 3.0969 3.0969 3.3084 3.3084 4.0470 3.3084 3.3084 4.0470 3.3084 4.0470 3.3084 1.0863 1.0863 1.0863
H6 2.5031 1.0863 3.3084 4.0470 3.3084 1.7543 1.7543 4.3072 3.1533 3.6084 4.9076 4.3072 4.3072 3.1533 4.3072 3.6084
H7 2.5031 1.0863 4.0470 3.3084 3.3084 1.7543 1.7543 4.9076 4.3072 4.3072 4.3072 3.6084 3.1533 3.6084 4.3072 3.1533
H8 2.5031 1.0863 3.3084 3.3084 4.0470 1.7543 1.7543 4.3072 3.6084 3.1533 4.3072 3.1533 3.6084 4.3072 4.9076 4.3072
H9 2.5031 4.0470 1.0863 3.3084 3.3084 4.3072 4.9076 4.3072 1.7543 1.7543 3.1533 3.6084 4.3072 3.6084 3.1533 4.3072
H10 2.5031 3.3084 1.0863 4.0470 3.3084 3.1533 4.3072 3.6084 1.7543 1.7543 4.3072 4.3072 4.9076 3.1533 3.6084 4.3072
H11 2.5031 3.3084 1.0863 3.3084 4.0470 3.6084 4.3072 3.1533 1.7543 1.7543 3.6084 3.1533 4.3072 4.3072 4.3072 4.9076
H12 2.5031 4.0470 3.3084 1.0863 3.3084 4.9076 4.3072 4.3072 3.1533 4.3072 3.6084 1.7543 1.7543 4.3072 3.1533 3.6084
H13 2.5031 3.3084 3.3084 1.0863 4.0470 4.3072 3.6084 3.1533 3.6084 4.3072 3.1533 1.7543 1.7543 4.9076 4.3072 4.3072
H14 2.5031 3.3084 4.0470 1.0863 3.3084 4.3072 3.1533 3.6084 4.3072 4.9076 4.3072 1.7543 1.7543 4.3072 3.6084 3.1533
H15 2.5031 3.3084 3.3084 4.0470 1.0863 3.1533 3.6084 4.3072 3.6084 3.1533 4.3072 4.3072 4.9076 4.3072 1.7543 1.7543
H16 2.5031 4.0470 3.3084 3.3084 1.0863 4.3072 4.3072 4.9076 3.1533 3.6084 4.3072 3.1533 4.3072 3.6084 1.7543 1.7543
H17 2.5031 3.3084 4.0470 3.3084 1.0863 3.6084 3.1533 4.3072 4.3072 4.3072 4.9076 3.6084 4.3072 3.1533 1.7543 1.7543
Maximum atom distance is 4.9076Å between atoms H6 and H12.
picture of tetramethylsilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C2 Si1 C3 109.471 C2 Si1 C4 109.471
C2 Si1 C5 109.471 C3 Si1 C4 109.471
C3 Si1 C5 109.471 C4 Si1 C5 109.471
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Si1 C2 H6 111.187 Si1 C2 H7 111.187
Si1 C2 H8 111.187 Si1 C3 H9 111.187
Si1 C3 H10 111.187 Si1 C3 H11 111.187
Si1 C4 H12 111.187 Si1 C4 H13 111.187
Si1 C4 H14 111.187 Si1 C5 H15 111.187
Si1 C5 H16 111.187 Si1 C5 H17 111.187
H6 C2 H7 107.702 H6 C2 H8 107.702
H7 C2 H8 107.702 H9 C3 H10 107.702
H9 C3 H11 107.702 H10 C3 H11 107.702
H12 C4 H13 107.702 H12 C4 H14 107.702
H13 C4 H14 107.702 H15 C5 H16 107.702
H15 C5 H17 107.702 H16 C5 H17 107.702

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.