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Geometry for (silicon pentafluoride anion) 1A1' D3H

1910171554
InChI=1S/F5Si/c1-6(2,3,4)5/q-1 INChIKey=

MP2/Def2TZVPP


Point group is D3h
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
F2 0.0000 0.0000 1.6720   1.6720 0.0000 0.0000
F3 0.0000 1.6306 0.0000   0.0000 1.6306 0.0000
F4 1.4121 -0.8153 0.0000   0.0000 -0.8153 1.4121
F5 -1.4121 -0.8153 0.0000   0.0000 -0.8153 -1.4121
F6 0.0000 0.0000 -1.6720   -1.6720 0.0000 0.0000
Atom - Atom Distances (Å)
  Si1 F2 F3 F4 F5 F6
Si1 1.6720 1.6306 1.6306 1.6306 1.6720
F2 1.6720 2.3354 2.3354 2.3354 3.3440
F3 1.6306 2.3354 2.8242 2.8242 2.3354
F4 1.6306 2.3354 2.8242 2.8242 2.3354
F5 1.6306 2.3354 2.8242 2.8242 2.3354
F6 1.6720 3.3440 2.3354 2.3354 2.3354
Maximum atom distance is 3.3440Å between atoms F2 and F6.
picture of silicon pentafluoride anion
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 Si1 F3 90.000 F2 Si1 F4 90.000
F2 Si1 F5 90.000 F2 Si1 F6 180.000
F3 Si1 F4 120.000 F3 Si1 F5 120.000
F3 Si1 F6 90.000 F4 Si1 F5 120.000
F4 Si1 F6 90.000 F5 Si1 F6 90.000

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.