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Computational Chemistry Comparison and Benchmark DataBase
Release 22 (May 2022) Standard Reference Database 101
National Institute of Standards and Technology
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You are here: Home > Geometry > Calculated > Calculated geometry OR Calculated > Geometry > Calculated geometry
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Geometry for CH3CCCH3 (2-Butyne)
1A1' D3H
1910171554
InChI=1S/C4H6/c1-3-4-2/h1-2H3 INChIKey=XNMQEEKYCVKGBD-UHFFFAOYSA-N
HF/Def2TZVPP
Point group is D3h
| Atom |
Internal |
|
Principal |
| x (Å) |
y (Å) |
z (Å) |
|
a (Å) |
b (Å) |
c (Å) |
| C1 |
0.0000 |
0.0000 |
0.5910 |
|
0.5910 |
0.0000 |
0.0000 |
| C2 |
0.0000 |
0.0000 |
-0.5910 |
|
-0.5910 |
0.0000 |
0.0000 |
| C3 |
0.0000 |
0.0000 |
2.0563 |
|
2.0563 |
0.0000 |
0.0000 |
| C4 |
0.0000 |
0.0000 |
-2.0563 |
|
-2.0563 |
0.0000 |
0.0000 |
| H5 |
0.0000 |
1.0129 |
2.4375 |
|
2.4375 |
0.2731 |
0.9753 |
| H6 |
-0.8772 |
-0.5064 |
2.4375 |
|
2.4375 |
-0.9812 |
-0.2512 |
| H7 |
0.8772 |
-0.5064 |
2.4375 |
|
2.4375 |
0.7081 |
-0.7242 |
| H8 |
0.0000 |
1.0129 |
-2.4375 |
|
-2.4375 |
0.2731 |
0.9753 |
| H9 |
0.8772 |
-0.5064 |
-2.4375 |
|
-2.4375 |
0.7081 |
-0.7242 |
| H10 |
-0.8772 |
-0.5064 |
-2.4375 |
|
-2.4375 |
-0.9812 |
-0.2512 |
Atom - Atom Distances (Å)
| |
C1 |
C2 |
C3 |
C4 |
H5 |
H6 |
H7 |
H8 |
H9 |
H10 |
| C1 |
|
1.1821 |
1.4652 |
2.6473 |
2.1060 |
2.1060 |
2.1060 |
3.1935 |
3.1935 |
3.1935 |
| C2 |
1.1821 |
| 2.6473 |
1.4652 |
3.1935 |
3.1935 |
3.1935 |
2.1060 |
2.1060 |
2.1060 |
| C3 |
1.4652 |
2.6473 |
| 4.1125 |
1.0822 |
1.0822 |
1.0822 |
4.6065 |
4.6065 |
4.6065 |
| C4 |
2.6473 |
1.4652 |
4.1125 |
| 4.6065 |
4.6065 |
4.6065 |
1.0822 |
1.0822 |
1.0822 |
| H5 |
2.1060 |
3.1935 |
1.0822 |
4.6065 |
| 1.7543 |
1.7543 |
4.8751 |
5.1811 |
5.1811 |
| H6 |
2.1060 |
3.1935 |
1.0822 |
4.6065 |
1.7543 |
| 1.7543 |
5.1811 |
5.1811 |
4.8751 |
| H7 |
2.1060 |
3.1935 |
1.0822 |
4.6065 |
1.7543 |
1.7543 |
| 5.1811 |
4.8751 |
5.1811 |
| H8 |
3.1935 |
2.1060 |
4.6065 |
1.0822 |
4.8751 |
5.1811 |
5.1811 |
| 1.7543 |
1.7543 |
| H9 |
3.1935 |
2.1060 |
4.6065 |
1.0822 |
5.1811 |
5.1811 |
4.8751 |
1.7543 |
| 1.7543 |
| H10 |
3.1935 |
2.1060 |
4.6065 |
1.0822 |
5.1811 |
4.8751 |
5.1811 |
1.7543 |
1.7543 |
|
Maximum atom distance is 5.1811Å
between atoms H6 and H9.
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
| atom1 |
atom2 |
atom3 |
angle |
|
atom1 |
atom2 |
atom3 |
angle |
|
C1 |
C2 |
C4 |
180.000 |
|
C2 |
C1 |
C3 |
180.000 |
Calculated Bond Angles (degrees) (Involving Hydrogens)
| atom1 |
atom2 |
atom3 |
angle |
|
atom1 |
atom2 |
atom3 |
angle |
|
C1 |
C3 |
H5 |
110.628 |
|
C1 |
C3 |
H6 |
110.628 |
|
C1 |
C3 |
H7 |
110.628 |
|
C2 |
C4 |
H8 |
110.628 |
|
C2 |
C4 |
H9 |
110.628 |
|
C2 |
C4 |
H10 |
110.628 |
|
H5 |
C3 |
H6 |
108.291 |
|
H5 |
C3 |
H7 |
108.291 |
|
H6 |
C3 |
H7 |
108.291 |
|
H8 |
C4 |
H9 |
108.291 |
|
H8 |
C4 |
H10 |
108.291 |
|
H9 |
C4 |
H10 |
108.291 |
For information on specific bond angles or dihedrals
see the geometry comparison page in section
Comparisons > Geometry > Bonds, angles.