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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

CCSD(T)/Def2TZVPP


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3781   0.0000 0.0000 0.3781
F2 0.0000 1.6419 0.2709   1.6419 0.0000 0.2709
F3 0.0000 -1.6419 0.2709   -1.6419 0.0000 0.2709
F4 1.1983 0.0000 -0.6070   0.0000 1.1983 -0.6070
F5 -1.1983 0.0000 -0.6070   0.0000 -1.1983 -0.6070
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6454 1.6454 1.5512 1.5512
F2 1.6454 3.2838 2.2141 2.2141
F3 1.6454 3.2838 2.2141 2.2141
F4 1.5512 2.2141 2.2141 2.3965
F5 1.5512 2.2141 2.2141 2.3965
Maximum atom distance is 3.2838Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 172.528 F2 S1 F4 87.628
F2 S1 F5 87.628 F3 S1 F4 87.628
F3 S1 F5 87.628 F4 S1 F5 101.152

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.