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Geometry for CH3NHNHCH3 (dimethyl hydrazine) 1A C2

1910171554
InChI=1S/C2H8N2/c1-3-4-2/h3-4H,1-2H3 INChIKey=DIIIISSCIXVANO-UHFFFAOYSA-N

MP2/6-31+G**


Point group is C2
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
N1 -0.1546 0.6965 -0.6880   -0.6818 -0.1798 0.6965
N2 0.1546 -0.6965 -0.6880   -0.6932 0.1292 -0.6965
C3 0.1546 1.4337 0.5363   0.5303 0.1742 1.4337
C4 -0.1546 -1.4337 0.5363   0.5416 -0.1348 -1.4337
H5 -1.1392 0.7762 -0.9184   -0.8759 -1.1722 0.7762
H6 1.1392 -0.7762 -0.9184   -0.9596 1.1047 -0.7762
H7 -0.1071 2.4771 0.3646   0.3683 -0.0936 2.4771
H8 -0.3689 1.0882 1.4340   1.4466 -0.3159 1.0882
H9 1.2283 1.3785 0.7176   0.6720 1.2539 1.3785
H10 0.1071 -2.4771 0.3646   0.3605 0.1205 -2.4771
H11 0.3689 -1.0882 1.4340   1.4195 0.4213 -1.0882
H12 -1.2283 -1.3785 0.7176   0.7623 -1.2011 -1.3785
Atom - Atom Distances (Å)
  N1 N2 C3 C4 H5 H6 H7 H8 H9 H10 H11 H12
N1 1.4269 1.4622 2.4569 1.0143 1.9737 2.0690 2.1685 2.0865 3.3538 2.8217 2.7266
N2 1.4269 2.4569 1.4622 1.9737 1.0143 3.3538 2.8217 2.7266 2.0690 2.1685 2.0865
C3 1.4622 2.4569 2.8839 2.0548 2.8229 1.0893 1.0951 1.0903 3.9148 2.6854 3.1390
C4 2.4569 1.4622 2.8839 2.8229 2.0548 3.9148 2.6854 3.1390 1.0893 1.0951 1.0903
H5 1.0143 1.9737 2.0548 2.8229 2.7569 2.3674 2.4949 2.9401 3.7125 3.3591 2.7068
H6 1.9737 1.0143 2.8229 2.0548 2.7569 3.7125 3.3591 2.7068 2.3674 2.4949 2.9401
H7 2.0690 3.3538 1.0893 3.9148 2.3674 3.7125 1.7723 1.7649 4.9588 3.7525 4.0308
H8 2.1685 2.8217 1.0951 2.6854 2.4949 3.3591 1.7723 1.7744 3.7525 2.2980 2.7086
H9 2.0865 2.7266 1.0903 3.1390 2.9401 2.7068 1.7649 1.7744 4.0308 2.7086 3.6927
H10 3.3538 2.0690 3.9148 1.0893 3.7125 2.3674 4.9588 3.7525 4.0308 1.7723 1.7649
H11 2.8217 2.1685 2.6854 1.0951 3.3591 2.4949 3.7525 2.2980 2.7086 1.7723 1.7744
H12 2.7266 2.0865 3.1390 1.0903 2.7068 2.9401 4.0308 2.7086 3.6927 1.7649 1.7744
Maximum atom distance is 4.9588Å between atoms H7 and H10.
picture of dimethyl hydrazine
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 C4 116.511 N2 N1 C3 116.511
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 H6 106.679 N1 C3 H7 107.467
N1 C3 H8 115.231 N1 C3 H9 108.781
N2 N1 H5 106.679 N2 C4 H10 107.467
N2 C4 H11 115.231 N2 C4 H12 108.781
C3 N1 H5 110.845 C4 N2 H6 110.845
H7 C3 H8 108.453 H7 C3 H9 108.135
H8 C3 H9 108.569 H10 C4 H11 108.453
H10 C4 H12 108.135 H11 C4 H12 108.569

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.