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Geometry for B2H4 (Diborane(4) D2d) 1A1 D2D

1910171554
InChI=1S/B2H4/c1-2/h1-2H2 INChIKey=QSJRRLWJRLPVID-UHFFFAOYSA-N

BLYP/cc-pVDZ


Point group is D2d
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
B1 0.0000 0.0000 0.8180   0.8180 0.0000 0.0000
B2 0.0000 0.0000 -0.8180   -0.8180 0.0000 0.0000
H3 0.0000 1.0290 1.4705   1.4705 1.0290 0.0000
H4 0.0000 -1.0290 1.4705   1.4705 -1.0290 0.0000
H5 1.0290 0.0000 -1.4705   -1.4705 0.0000 1.0290
H6 -1.0290 0.0000 -1.4705   -1.4705 0.0000 -1.0290
Atom - Atom Distances (Å)
  B1 B2 H3 H4 H5 H6
B1 1.6360 1.2184 1.2184 2.5092 2.5092
B2 1.6360 2.5092 2.5092 1.2184 1.2184
H3 1.2184 2.5092 2.0579 3.2814 3.2814
H4 1.2184 2.5092 2.0579 3.2814 3.2814
H5 2.5092 1.2184 3.2814 3.2814 2.0579
H6 2.5092 1.2184 3.2814 3.2814 2.0579
Maximum atom distance is 3.2814Å between atoms H3 and H5.
picture of Diborane(4) D2d
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
B1 B2 H5 122.381 B1 B2 H6 122.381
B2 B1 H3 122.381 B2 B1 H4 122.381
H3 B1 H4 115.237 H5 B2 H6 115.237

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.