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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

B3PW91/cc-pVDZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3903   0.0000 0.0000 0.3903
F2 0.0000 1.6846 0.2846   1.6846 0.0000 0.2846
F3 0.0000 -1.6846 0.2846   -1.6846 0.0000 0.2846
F4 1.2397 0.0000 -0.6316   0.0000 1.2397 -0.6316
F5 -1.2397 0.0000 -0.6316   0.0000 -1.2397 -0.6316
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6880 1.6880 1.6066 1.6066
F2 1.6880 3.3693 2.2835 2.2835
F3 1.6880 3.3693 2.2835 2.2835
F4 1.6066 2.2835 2.2835 2.4793
F5 1.6066 2.2835 2.2835 2.4793
Maximum atom distance is 3.3693Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 172.819 F2 S1 F4 87.717
F2 S1 F5 87.717 F3 S1 F4 87.717
F3 S1 F5 87.717 F4 S1 F5 101.000

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.