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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

B3LYP/cc-pVTZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3826   0.0000 0.0000 0.3826
F2 0.0000 1.6729 0.2778   1.6729 0.0000 0.2778
F3 0.0000 -1.6729 0.2778   -1.6729 0.0000 0.2778
F4 1.2171 0.0000 -0.6179   0.0000 1.2171 -0.6179
F5 -1.2171 0.0000 -0.6179   0.0000 -1.2171 -0.6179
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6762 1.6762 1.5755 1.5755
F2 1.6762 3.3459 2.2544 2.2544
F3 1.6762 3.3459 2.2544 2.2544
F4 1.5755 2.2544 2.2544 2.4341
F5 1.5755 2.2544 2.2544 2.4341
Maximum atom distance is 3.3459Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 172.831 F2 S1 F4 87.725
F2 S1 F5 87.725 F3 S1 F4 87.725
F3 S1 F5 87.725 F4 S1 F5 101.159

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.