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Geometry for Cl3PO (Phosphoryl chloride) 1A1 C3V

1910171554
InChI=1S/Cl3OP/c1-5(2,3)4 INChIKey=XHXFXVLFKHQFAL-UHFFFAOYSA-N

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Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
P1 0.0000 0.0000 0.4240   0.0000 0.0000 0.4240
O2 0.0000 0.0000 1.8837   0.0000 0.0000 1.8837
Cl3 0.0000 1.8254 -0.4202   1.8254 0.0000 -0.4202
Cl4 1.5808 -0.9127 -0.4202   -0.9127 1.5808 -0.4202
Cl5 -1.5808 -0.9127 -0.4202   -0.9127 -1.5808 -0.4202
Atom - Atom Distances (Å)
  P1 O2 Cl3 Cl4 Cl5
P1 1.4597 2.0111 2.0111 2.0111
O2 1.4597 2.9394 2.9394 2.9394
Cl3 2.0111 2.9394 3.1617 3.1617
Cl4 2.0111 2.9394 3.1617 3.1617
Cl5 2.0111 2.9394 3.1617 3.1617
Maximum atom distance is 3.1617Å between atoms Cl4 and Cl5.
picture of Phosphoryl chloride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
O2 P1 Cl3 114.819 O2 P1 Cl4 114.819
O2 P1 Cl5 114.819 Cl3 P1 Cl4 103.634
Cl3 P1 Cl5 103.634 Cl4 P1 Cl5 103.634

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.