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Geometry for Si(CH3)4 (tetramethylsilane) 1A1 TD

1910171554
InChI=1S/C4H12Si/c1-5(2,3)4/h1-4H3 INChIKey=CZDYPVPMEAXLPK-UHFFFAOYSA-N

HSEh1PBE/cc-pVTZ


Point group is Td
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
C2 1.0876 1.0876 1.0876   1.1564 1.0141 1.0876
C3 -1.0876 -1.0876 1.0876   -1.1564 -1.0141 1.0876
C4 -1.0876 1.0876 -1.0876   -1.0141 1.1564 -1.0876
C5 1.0876 -1.0876 -1.0876   1.0141 -1.1564 -1.0876
H6 1.7309 0.4830 1.7309   1.7588 0.3687 1.7309
H7 1.7309 1.7309 0.4830   1.8404 1.6139 0.4830
H8 0.4830 1.7309 1.7309   0.5952 1.6956 1.7309
H9 -1.7309 -1.7309 0.4830   -1.8404 -1.6139 0.4830
H10 -0.4830 -1.7309 1.7309   -0.5952 -1.6956 1.7309
H11 -1.7309 -0.4830 1.7309   -1.7588 -0.3687 1.7309
H12 -1.7309 0.4830 -1.7309   -1.6956 0.5952 -1.7309
H13 -1.7309 1.7309 -0.4830   -1.6139 1.8404 -0.4830
H14 -0.4830 1.7309 -1.7309   -0.3687 1.7588 -1.7309
H15 1.7309 -1.7309 -0.4830   1.6139 -1.8404 -0.4830
H16 0.4830 -1.7309 -1.7309   0.3687 -1.7588 -1.7309
H17 1.7309 -0.4830 -1.7309   1.6956 -0.5952 -1.7309
Atom - Atom Distances (Å)
  Si1 C2 C3 C4 C5 H6 H7 H8 H9 H10 H11 H12 H13 H14 H15 H16 H17
Si1 1.8838 1.8838 1.8838 1.8838 2.4950 2.4950 2.4950 2.4950 2.4950 2.4950 2.4950 2.4950 2.4950 2.4950 2.4950 2.4950
C2 1.8838 3.0762 3.0762 3.0762 1.0923 1.0923 1.0923 4.0315 3.2900 3.2900 4.0315 3.2900 3.2900 3.2900 4.0315 3.2900
C3 1.8838 3.0762 3.0762 3.0762 3.2900 4.0315 3.2900 1.0923 1.0923 1.0923 3.2900 3.2900 4.0315 3.2900 3.2900 4.0315
C4 1.8838 3.0762 3.0762 3.0762 4.0315 3.2900 3.2900 3.2900 4.0315 3.2900 1.0923 1.0923 1.0923 4.0315 3.2900 3.2900
C5 1.8838 3.0762 3.0762 3.0762 3.2900 3.2900 4.0315 3.2900 3.2900 4.0315 3.2900 4.0315 3.2900 1.0923 1.0923 1.0923
H6 2.4950 1.0923 3.2900 4.0315 3.2900 1.7648 1.7648 4.2944 3.1308 3.5940 4.8957 4.2944 4.2944 3.1308 4.2944 3.5940
H7 2.4950 1.0923 4.0315 3.2900 3.2900 1.7648 1.7648 4.8957 4.2944 4.2944 4.2944 3.5940 3.1308 3.5940 4.2944 3.1308
H8 2.4950 1.0923 3.2900 3.2900 4.0315 1.7648 1.7648 4.2944 3.5940 3.1308 4.2944 3.1308 3.5940 4.2944 4.8957 4.2944
H9 2.4950 4.0315 1.0923 3.2900 3.2900 4.2944 4.8957 4.2944 1.7648 1.7648 3.1308 3.5940 4.2944 3.5940 3.1308 4.2944
H10 2.4950 3.2900 1.0923 4.0315 3.2900 3.1308 4.2944 3.5940 1.7648 1.7648 4.2944 4.2944 4.8957 3.1308 3.5940 4.2944
H11 2.4950 3.2900 1.0923 3.2900 4.0315 3.5940 4.2944 3.1308 1.7648 1.7648 3.5940 3.1308 4.2944 4.2944 4.2944 4.8957
H12 2.4950 4.0315 3.2900 1.0923 3.2900 4.8957 4.2944 4.2944 3.1308 4.2944 3.5940 1.7648 1.7648 4.2944 3.1308 3.5940
H13 2.4950 3.2900 3.2900 1.0923 4.0315 4.2944 3.5940 3.1308 3.5940 4.2944 3.1308 1.7648 1.7648 4.8957 4.2944 4.2944
H14 2.4950 3.2900 4.0315 1.0923 3.2900 4.2944 3.1308 3.5940 4.2944 4.8957 4.2944 1.7648 1.7648 4.2944 3.5940 3.1308
H15 2.4950 3.2900 3.2900 4.0315 1.0923 3.1308 3.5940 4.2944 3.5940 3.1308 4.2944 4.2944 4.8957 4.2944 1.7648 1.7648
H16 2.4950 4.0315 3.2900 3.2900 1.0923 4.2944 4.2944 4.8957 3.1308 3.5940 4.2944 3.1308 4.2944 3.5940 1.7648 1.7648
H17 2.4950 3.2900 4.0315 3.2900 1.0923 3.5940 3.1308 4.2944 4.2944 4.2944 4.8957 3.5940 4.2944 3.1308 1.7648 1.7648
Maximum atom distance is 4.8957Å between atoms H6 and H12.
picture of tetramethylsilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C2 Si1 C3 109.471 C2 Si1 C4 109.471
C2 Si1 C5 109.471 C3 Si1 C4 109.471
C3 Si1 C5 109.471 C4 Si1 C5 109.471
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Si1 C2 H6 111.127 Si1 C2 H7 111.127
Si1 C2 H8 111.127 Si1 C3 H9 111.127
Si1 C3 H10 111.127 Si1 C3 H11 111.127
Si1 C4 H12 111.127 Si1 C4 H13 111.127
Si1 C4 H14 111.127 Si1 C5 H15 111.127
Si1 C5 H16 111.127 Si1 C5 H17 111.127
H6 C2 H7 107.766 H6 C2 H8 107.766
H7 C2 H8 107.766 H9 C3 H10 107.766
H9 C3 H11 107.766 H10 C3 H11 107.766
H12 C4 H13 107.766 H12 C4 H14 107.766
H13 C4 H14 107.766 H15 C5 H16 107.766
H15 C5 H17 107.766 H16 C5 H17 107.766

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.