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Geometry for SOF4 (Sulfur tetrafluoride oxide) 1A1 C2V

1910171554
InChI=1S/F4OS/c1-6(2,3,4)5 INChIKey=DUGWRBKBGKTKOX-UHFFFAOYSA-N

QCISD/6-311G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.1412   0.0000 0.0000 0.1412
O2 0.0000 0.0000 1.5605   0.0000 0.0000 1.5605
F3 0.0000 1.6050 -0.0826   1.6050 0.0000 -0.0826
F4 0.0000 -1.6050 -0.0826   -1.6050 0.0000 -0.0826
F5 1.3016 0.0000 -0.7365   0.0000 1.3016 -0.7365
F6 -1.3016 0.0000 -0.7365   0.0000 -1.3016 -0.7365
Atom - Atom Distances (Å)
  S1 O2 F3 F4 F5 F6
S1 1.4193 1.6205 1.6205 1.5699 1.5699
O2 1.4193 2.2969 2.2969 2.6402 2.6402
F3 1.6205 2.2969 3.2099 2.1674 2.1674
F4 1.6205 2.2969 3.2099 2.1674 2.1674
F5 1.5699 2.6402 2.1674 2.1674 2.6032
F6 1.5699 2.6402 2.1674 2.1674 2.6032
Maximum atom distance is 3.2099Å between atoms F3 and F4.
picture of Sulfur tetrafluoride oxide
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
O2 S1 F3 97.939 O2 S1 F4 97.939
O2 S1 F5 123.995 O2 S1 F6 123.995
F3 S1 F4 164.121 F3 S1 F5 85.571
F3 S1 F6 85.571 F4 S1 F5 85.571
F4 S1 F6 85.571 F5 S1 F6 112.011

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.