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Geometry for S2F10 (disulphur decafluoride) 1A1 D4D

1910171554
InChI=1S/F10S2/c1-11(2,3,4,5)12(6,7,8,9)10 INChIKey=

B2PLYP=FULLultrafine/3-21G*


Point group is D4d
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 1.0911   1.0911 0.0000 0.0000
S2 0.0000 0.0000 -1.0911   -1.0911 0.0000 0.0000
F3 0.0000 1.5953 1.0969   1.0969 1.5953 0.0000
F4 -1.5953 0.0000 1.0969   1.0969 0.0000 -1.5953
F5 0.0000 -1.5953 1.0969   1.0969 -1.5953 0.0000
F6 1.5953 0.0000 1.0969   1.0969 0.0000 1.5953
F7 0.0000 0.0000 2.6730   2.6730 0.0000 0.0000
F8 1.1281 1.1281 -1.0969   -1.0969 1.1281 1.1281
F9 1.1281 -1.1281 -1.0969   -1.0969 -1.1281 1.1281
F10 -1.1281 -1.1281 -1.0969   -1.0969 -1.1281 -1.1281
F11 -1.1281 1.1281 -1.0969   -1.0969 1.1281 -1.1281
F12 0.0000 0.0000 -2.6730   -2.6730 0.0000 0.0000
Atom - Atom Distances (Å)
  S1 S2 F3 F4 F5 F6 F7 F8 F9 F10 F11 F12
S1 2.1823 1.5953 1.5953 1.5953 1.5953 1.5819 2.7079 2.7079 2.7079 2.7079 3.7642
S2 2.1823 2.7079 2.7079 2.7079 2.7079 3.7642 1.5953 1.5953 1.5953 1.5953 1.5819
F3 1.5953 2.7079 2.2561 3.1907 2.2561 2.2426 2.5107 3.6745 3.6745 2.5107 4.0936
F4 1.5953 2.7079 2.2561 2.2561 3.1907 2.2426 3.6745 3.6745 2.5107 2.5107 4.0936
F5 1.5953 2.7079 3.1907 2.2561 2.2561 2.2426 3.6745 2.5107 2.5107 3.6745 4.0936
F6 1.5953 2.7079 2.2561 3.1907 2.2561 2.2426 2.5107 2.5107 3.6745 3.6745 4.0936
F7 1.5819 3.7642 2.2426 2.2426 2.2426 2.2426 4.0936 4.0936 4.0936 4.0936 5.3461
F8 2.7079 1.5953 2.5107 3.6745 3.6745 2.5107 4.0936 2.2561 3.1907 2.2561 2.2426
F9 2.7079 1.5953 3.6745 3.6745 2.5107 2.5107 4.0936 2.2561 2.2561 3.1907 2.2426
F10 2.7079 1.5953 3.6745 2.5107 2.5107 3.6745 4.0936 3.1907 2.2561 2.2561 2.2426
F11 2.7079 1.5953 2.5107 2.5107 3.6745 3.6745 4.0936 2.2561 3.1907 2.2561 2.2426
F12 3.7642 1.5819 4.0936 4.0936 4.0936 4.0936 5.3461 2.2426 2.2426 2.2426 2.2426
Maximum atom distance is 5.3461Å between atoms F7 and F12.
picture of disulphur decafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 F8 90.206 S1 S2 F9 90.206
S1 S2 F10 90.206 S1 S2 F11 90.206
S1 S2 F12 180.000 S2 S1 F3 90.206
S2 S1 F4 90.206 S2 S1 F5 90.206
S2 S1 F6 90.206 S2 S1 F7 180.000
F3 S1 F4 89.999 F3 S1 F5 179.588
F3 S1 F6 89.999 F3 S1 F7 89.794
F4 S1 F5 89.999 F4 S1 F6 179.588
F4 S1 F7 89.794 F5 S1 F6 89.999
F5 S1 F7 89.794 F6 S1 F7 89.794
F8 S2 F9 89.999 F8 S2 F10 179.588
F8 S2 F11 89.999 F8 S2 F12 89.794
F9 S2 F10 89.999 F9 S2 F11 179.588
F9 S2 F12 89.794 F10 S2 F11 89.999
F10 S2 F12 89.794 F11 S2 F12 89.794

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.