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Geometry for Si3H8 (trisilane) 1A1 C2V

1910171554
InChI=1S/H8Si3/c1-3-2/h3H2,1-2H3 INChIKey=VEDJZFSRVVQBIL-UHFFFAOYSA-N

HF/daug-cc-pVDZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.9036   0.9036 0.0000 0.0000
Si2 0.0000 1.9703 -0.4253   -0.4253 0.0000 1.9703
Si3 0.0000 -1.9703 -0.4253   -0.4253 0.0000 -1.9703
H4 1.2071 0.0000 1.7797   1.7797 1.2071 0.0000
H5 -1.2071 0.0000 1.7797   1.7797 -1.2071 0.0000
H6 0.0000 3.1833 0.4374   0.4374 0.0000 3.1833
H7 0.0000 -3.1833 0.4374   0.4374 0.0000 -3.1833
H8 1.2092 2.0012 -1.2937   -1.2937 1.2092 2.0012
H9 -1.2092 2.0012 -1.2937   -1.2937 -1.2092 2.0012
H10 -1.2092 -2.0012 -1.2937   -1.2937 -1.2092 -2.0012
H11 1.2092 -2.0012 -1.2937   -1.2937 1.2092 -2.0012
Atom - Atom Distances (Å)
  Si1 Si2 Si3 H4 H5 H6 H7 H8 H9 H10 H11
Si1 2.3766 2.3766 1.4915 1.4915 3.2172 3.2172 3.2086 3.2086 3.2086 3.2086
Si2 2.3766 3.9406 3.1939 3.1939 1.4885 5.2253 1.4890 1.4890 4.2414 4.2414
Si3 2.3766 3.9406 3.1939 3.1939 5.2253 1.4885 4.2414 4.2414 1.4890 1.4890
H4 1.4915 3.1939 3.1939 2.4142 3.6595 3.6595 3.6675 4.3919 4.3919 3.6675
H5 1.4915 3.1939 3.1939 2.4142 3.6595 3.6595 4.3919 3.6675 3.6675 4.3919
H6 3.2172 1.4885 5.2253 3.6595 3.6595 6.3665 2.4200 2.4200 5.5980 5.5980
H7 3.2172 5.2253 1.4885 3.6595 3.6595 6.3665 5.5980 5.5980 2.4200 2.4200
H8 3.2086 1.4890 4.2414 3.6675 4.3919 2.4200 5.5980 2.4183 4.6763 4.0025
H9 3.2086 1.4890 4.2414 4.3919 3.6675 2.4200 5.5980 2.4183 4.0025 4.6763
H10 3.2086 4.2414 1.4890 4.3919 3.6675 5.5980 2.4200 4.6763 4.0025 2.4183
H11 3.2086 4.2414 1.4890 3.6675 4.3919 5.5980 2.4200 4.0025 4.6763 2.4183
Maximum atom distance is 6.3665Å between atoms H6 and H7.
picture of trisilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S2 S1 S3 112.002
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 H6 110.578 S1 S2 H8 110.080
S1 S2 H9 110.080 S1 S3 H7 110.578
S1 S3 H10 110.080 S1 S3 H11 110.080
S2 S1 H4 109.174 S2 S1 H5 109.174
S3 S1 H4 109.174 S3 S1 H5 109.174
H4 S1 H5 108.059 H6 S2 H8 108.730
H6 S2 H9 108.730 H7 S3 H10 108.730
H7 S3 H11 108.730 H8 S2 H9 108.595
H10 S3 H11 108.595

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.