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Geometry for CH3MgBr (Methyl Magnesium Bromide) 1A1 C3V

1910171554
InChI=1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1 INChIKey=

PBEPBEultrafine/6-311+G(3df,2p)


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
C1 0.0000 0.0000 -3.2000   -3.2000 0.0000 -0.0000
Mg2 0.0000 0.0000 -1.1193   -1.1193 0.0000 -0.0000
Br3 0.0000 0.0000 1.2407   1.2407 0.0000 0.0000
H4 0.0000 1.0250 -3.5982   -3.5982 -1.0250 -0.0000
H5 0.8877 -0.5125 -3.5982   -3.5982 0.5125 -0.8877
H6 -0.8877 -0.5125 -3.5982   -3.5982 0.5125 0.8877
Atom - Atom Distances (Å)
  C1 Mg2 Br3 H4 H5 H6
C1 2.0807 4.4407 1.0997 1.0997 1.0997
Mg2 2.0807 2.3600 2.6825 2.6825 2.6825
Br3 4.4407 2.3600 4.9463 4.9463 4.9463
H4 1.0997 2.6825 4.9463 1.7754 1.7754
H5 1.0997 2.6825 4.9463 1.7754 1.7754
H6 1.0997 2.6825 4.9463 1.7754 1.7754
Maximum atom distance is 4.9463Å between atoms Br3 and H4.
picture of Methyl Magnesium Bromide
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C1 Mg2 Br3 180.000
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Mg2 C1 H4 111.233 Mg2 C1 H5 111.233
Mg2 C1 H6 111.233 H4 C1 H5 107.653
H4 C1 H6 107.653 H5 C1 H6 107.653

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.