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Geometry for AsCl3 (Arsenous trichloride) 1A1 C3V

1910171554
1S/AsCl3/c2-1(3)4 INChIKey=OEYOHULQRFXULB-UHFFFAOYSA-N

CCSD/6-31G(2df,p)


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.6285   0.0000 0.0000 0.6285
Cl2 0.0000 1.8898 -0.4067   0.0000 1.8898 -0.4067
Cl3 1.6366 -0.9449 -0.4067   1.6366 -0.9449 -0.4067
Cl4 -1.6366 -0.9449 -0.4067   -1.6366 -0.9449 -0.4067
Atom - Atom Distances (Å)
  As1 Cl2 Cl3 Cl4
As1 2.1547 2.1547 2.1547
Cl2 2.1547 3.2732 3.2732
Cl3 2.1547 3.2732 3.2732
Cl4 2.1547 3.2732 3.2732
Maximum atom distance is 3.2732Å between atoms Cl2 and Cl3.
picture of Arsenous trichloride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 As1 Cl3 98.847 Cl2 As1 Cl4 98.847
Cl3 As1 Cl4 98.847

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.