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Geometry for Si3H8 (trisilane) 1A1 C2V

1910171554
InChI=1S/H8Si3/c1-3-2/h3H2,1-2H3 INChIKey=VEDJZFSRVVQBIL-UHFFFAOYSA-N

B1B95/6-311G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.8880   0.8880 0.0000 0.0000
Si2 0.0000 1.9363 -0.4176   -0.4176 0.0000 1.9363
Si3 0.0000 -1.9363 -0.4176   -0.4176 0.0000 -1.9363
H4 1.1999 0.0000 1.7673   1.7673 1.1999 0.0000
H5 -1.1999 0.0000 1.7673   1.7673 -1.1999 0.0000
H6 0.0000 3.1516 0.4351   0.4351 0.0000 3.1516
H7 0.0000 -3.1516 0.4351   0.4351 0.0000 -3.1516
H8 1.2035 1.9701 -1.2862   -1.2862 1.2035 1.9701
H9 -1.2035 1.9701 -1.2862   -1.2862 -1.2035 1.9701
H10 -1.2035 -1.9701 -1.2862   -1.2862 -1.2035 -1.9701
H11 1.2035 -1.9701 -1.2862   -1.2862 1.2035 -1.9701
Atom - Atom Distances (Å)
  Si1 Si2 Si3 H4 H5 H6 H7 H8 H9 H10 H11
Si1 2.3354 2.3354 1.4876 1.4876 3.1840 3.1840 3.1712 3.1712 3.1712 3.1712
Si2 2.3354 3.8727 3.1564 3.1564 1.4846 5.1589 1.4846 1.4846 4.1789 4.1789
Si3 2.3354 3.8727 3.1564 3.1564 5.1589 1.4846 4.1789 4.1789 1.4846 1.4846
H4 1.4876 3.1564 3.1564 2.3998 3.6259 3.6259 3.6338 4.3567 4.3567 3.6338
H5 1.4876 3.1564 3.1564 2.3998 3.6259 3.6259 4.3567 3.6338 3.6338 4.3567
H6 3.1840 1.4846 5.1589 3.6259 3.6259 6.3032 2.4098 2.4098 5.5356 5.5356
H7 3.1840 5.1589 1.4846 3.6259 3.6259 6.3032 5.5356 5.5356 2.4098 2.4098
H8 3.1712 1.4846 4.1789 3.6338 4.3567 2.4098 5.5356 2.4070 4.6172 3.9402
H9 3.1712 1.4846 4.1789 4.3567 3.6338 2.4098 5.5356 2.4070 3.9402 4.6172
H10 3.1712 4.1789 1.4846 4.3567 3.6338 5.5356 2.4098 4.6172 3.9402 2.4070
H11 3.1712 4.1789 1.4846 3.6338 4.3567 5.5356 2.4098 3.9402 4.6172 2.4070
Maximum atom distance is 6.3032Å between atoms H6 and H7.
picture of trisilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S2 S1 S3 112.021
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 H6 110.957 S1 S2 H8 110.239
S1 S2 H9 110.239 S1 S3 H7 110.957
S1 S3 H10 110.239 S1 S3 H11 110.239
S2 S1 H4 109.295 S2 S1 H5 109.295
S3 S1 H4 109.295 S3 S1 H5 109.295
H4 S1 H5 107.533 H6 S2 H8 108.508
H6 S2 H9 108.508 H7 S3 H10 108.508
H7 S3 H11 108.508 H8 S2 H9 108.320
H10 S3 H11 108.320

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.