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Geometry for N(SiH3)3 (trisilylamine) 1A' C3H

1910171554
InChI=1S/H9NSi3/c2-1(3)4/h2-4H3 INChIKey=

B1B95/cc-pVTZ


Point group is C3h
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
N1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
Si2 0.0000 1.7388 0.0000   1.7367 0.0856 0.0000
Si3 -1.5059 -0.8694 0.0000   -0.7942 -1.5468 0.0000
Si4 1.5059 -0.8694 0.0000   -0.9425 1.4612 0.0000
H5 -1.4184 2.1762 0.0000   2.2434 -1.3096 0.0000
H6 -1.1755 -2.3165 0.0000   -2.2558 -1.2881 0.0000
H7 2.5939 0.1403 0.0000   0.0124 2.5976 0.0000
H8 0.6801 2.2818 1.2013   2.2456 0.7916 1.2013
H9 0.6801 2.2818 -1.2013   2.2456 0.7916 -1.2013
H10 -2.3161 -0.5519 1.2013   -0.4373 -2.3405 1.2013
H11 -2.3161 -0.5519 -1.2013   -0.4373 -2.3405 -1.2013
H12 1.6361 -1.7299 1.2013   -1.8083 1.5489 1.2013
H13 1.6361 -1.7299 -1.2013   -1.8083 1.5489 -1.2013
Atom - Atom Distances (Å)
  N1 Si2 Si3 Si4 H5 H6 H7 H8 H9 H10 H11 H12 H13
N1 1.7388 1.7388 1.7388 2.5977 2.5977 2.5977 2.6669 2.6669 2.6669 2.6669 2.6669 2.6669
Si2 1.7388 3.0117 3.0117 1.4843 4.2222 3.0469 1.4834 1.4834 3.4721 3.4721 4.0189 4.0189
Si3 1.7388 3.0117 3.0117 3.0469 1.4843 4.2222 4.0189 4.0189 1.4834 1.4834 3.4721 3.4721
Si4 1.7388 3.0117 3.0117 4.2222 3.0469 1.4843 3.4721 3.4721 4.0189 4.0189 1.4834 1.4834
H5 2.5977 1.4843 3.0469 4.2222 4.4993 4.4993 2.4203 2.4203 3.1132 3.1132 5.1020 5.1020
H6 2.5977 4.2222 1.4843 3.0469 4.4993 4.4993 5.1020 5.1020 2.4203 2.4203 3.1132 3.1132
H7 2.5977 3.0469 4.2222 1.4843 4.4993 4.4993 3.1132 3.1132 5.1020 5.1020 2.4203 2.4203
H8 2.6669 1.4834 4.0189 3.4721 2.4203 5.1020 3.1132 2.4026 4.1240 4.7728 4.1240 4.7728
H9 2.6669 1.4834 4.0189 3.4721 2.4203 5.1020 3.1132 2.4026 4.7728 4.1240 4.7728 4.1240
H10 2.6669 3.4721 1.4834 4.0189 3.1132 2.4203 5.1020 4.1240 4.7728 2.4026 4.1240 4.7728
H11 2.6669 3.4721 1.4834 4.0189 3.1132 2.4203 5.1020 4.7728 4.1240 2.4026 4.7728 4.1240
H12 2.6669 4.0189 3.4721 1.4834 5.1020 3.1132 2.4203 4.1240 4.7728 4.1240 4.7728 2.4026
H13 2.6669 4.0189 3.4721 1.4834 5.1020 3.1132 2.4203 4.7728 4.1240 4.7728 4.1240 2.4026
Maximum atom distance is 5.1020Å between atoms H5 and H12.
picture of trisilylamine
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Si2 N1 Si3 120.000 Si2 N1 Si4 120.000
Si3 N1 Si4 120.000
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 Si2 H5 107.139 N1 Si2 H8 111.471
N1 Si2 H9 111.471 N1 Si3 H6 107.139
N1 Si3 H10 111.471 N1 Si3 H11 111.471
N1 Si4 H7 107.139 N1 Si4 H12 111.471
N1 Si4 H13 111.471 H5 Si2 H8 109.283
H5 Si2 H9 109.283 H6 Si3 H10 109.283
H6 Si3 H11 109.283 H7 Si4 H12 109.283
H7 Si4 H13 109.283 H8 Si2 H9 108.160
H10 Si3 H11 108.160 H12 Si4 H13 108.160

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.