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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

QCISD/aug-cc-pVDZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3948   0.0000 0.0000 0.3948
F2 0.0000 1.6923 0.2717   1.6923 0.0000 0.2717
F3 0.0000 -1.6923 0.2717   -1.6923 0.0000 0.2717
F4 1.2372 0.0000 -0.6226   0.0000 1.2372 -0.6226
F5 -1.2372 0.0000 -0.6226   0.0000 -1.2372 -0.6226
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6968 1.6968 1.6018 1.6018
F2 1.6968 3.3846 2.2791 2.2791
F3 1.6968 3.3846 2.2791 2.2791
F4 1.6018 2.2791 2.2791 2.4745
F5 1.6018 2.2791 2.2791 2.4745
Maximum atom distance is 3.3846Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 171.683 F2 S1 F4 87.360
F2 S1 F5 87.360 F3 S1 F4 87.360
F3 S1 F5 87.360 F4 S1 F5 101.140

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.