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Geometry for AsCl3 (Arsenous trichloride) 1A1 C3V

1910171554
1S/AsCl3/c2-1(3)4 INChIKey=OEYOHULQRFXULB-UHFFFAOYSA-N

B97D3/6-311+G(3df,2p)


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.6256   0.0000 0.0000 0.6256
Cl2 0.0000 1.9466 -0.4048   0.0000 1.9466 -0.4048
Cl3 1.6858 -0.9733 -0.4048   1.6858 -0.9733 -0.4048
Cl4 -1.6858 -0.9733 -0.4048   -1.6858 -0.9733 -0.4048
Atom - Atom Distances (Å)
  As1 Cl2 Cl3 Cl4
As1 2.2025 2.2025 2.2025
Cl2 2.2025 3.3716 3.3716
Cl3 2.2025 3.3716 3.3716
Cl4 2.2025 3.3716 3.3716
Maximum atom distance is 3.3716Å between atoms Cl3 and Cl4.
picture of Arsenous trichloride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 As1 Cl3 100.153 Cl2 As1 Cl4 100.153
Cl3 As1 Cl4 100.153

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.