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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

B3PW91/6-31G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3895   0.0000 0.0000 0.3895
F2 0.0000 1.6608 0.2644   1.6608 0.0000 0.2644
F3 0.0000 -1.6608 0.2644   -1.6608 0.0000 0.2644
F4 1.2338 0.0000 -0.6105   0.0000 1.2338 -0.6105
F5 -1.2338 0.0000 -0.6105   0.0000 -1.2338 -0.6105
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6655 1.6655 1.5881 1.5881
F2 1.6655 3.3215 2.2463 2.2463
F3 1.6655 3.3215 2.2463 2.2463
F4 1.5881 2.2463 2.2463 2.4675
F5 1.5881 2.2463 2.2463 2.4675
Maximum atom distance is 3.3215Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 171.385 F2 S1 F4 87.289
F2 S1 F5 87.289 F3 S1 F4 87.289
F3 S1 F5 87.289 F4 S1 F5 101.949

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.