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Geometry for SO2F2 (Sulfuryl fluoride) 1A1 C2V

1910171554
InChI=1S/F2O2S/c1-5(2,3)4 INChIKey=OBTWBSRJZRCYQV-UHFFFAOYSA-N

CCSD(T)=FULL/aug-cc-pVDZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.1840   0.1840 0.0000 0.0000
O2 0.0000 1.2978 0.8415   0.8415 1.2978 0.0000
O3 0.0000 -1.2978 0.8415   0.8415 -1.2978 0.0000
F4 1.1759 0.0000 -0.9116   -0.9116 0.0000 1.1759
F5 -1.1759 0.0000 -0.9116   -0.9116 0.0000 -1.1759
Atom - Atom Distances (Å)
  S1 O2 O3 F4 F5
S1 1.4549 1.4549 1.6072 1.6072
O2 1.4549 2.5956 2.4780 2.4780
O3 1.4549 2.5956 2.4780 2.4780
F4 1.6072 2.4780 2.4780 2.3518
F5 1.6072 2.4780 2.4780 2.3518
Maximum atom distance is 2.5956Å between atoms O2 and O3.
picture of Sulfuryl fluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
O2 S1 O3 126.259 O2 S1 F4 107.945
O2 S1 F5 107.945 O3 S1 F4 107.945
O3 S1 F5 107.945 F4 S1 F5 94.051

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.