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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

B3LYP/SDD


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.1968   0.0000 0.0000 0.1968
F2 0.0000 0.0000 -1.5093   0.0000 0.0000 -1.5093
F3 0.0000 1.8110 0.2899   1.4207 1.1231 0.2899
F4 -1.8110 0.0000 0.2899   1.1231 -1.4207 0.2899
F5 0.0000 -1.8110 0.2899   -1.4207 -1.1231 0.2899
F6 1.8110 0.0000 0.2899   -1.1231 1.4207 0.2899
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.7061 1.8134 1.8134 1.8134 1.8134
F2 1.7061 2.5528 2.5528 2.5528 2.5528
F3 1.8134 2.5528 2.5612 3.6221 2.5612
F4 1.8134 2.5528 2.5612 2.5612 3.6221
F5 1.8134 2.5528 3.6221 2.5612 2.5612
F6 1.8134 2.5528 2.5612 3.6221 2.5612
Maximum atom distance is 3.6221Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 92.941 F2 S1 F4 92.941
F2 S1 F5 92.941 F2 S1 F6 92.941
F3 S1 F4 89.849 F3 S1 F5 174.118
F3 S1 F6 89.849 F4 S1 F5 89.849
F4 S1 F6 174.118 F5 S1 F6 89.849

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.