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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

B2PLYP=FULLultrafine/TZVP


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3869   0.0000 0.0000 0.3869
F2 0.0000 1.6910 0.2808   1.6910 0.0000 0.2808
F3 0.0000 -1.6910 0.2808   -1.6910 0.0000 0.2808
F4 1.2261 0.0000 -0.6247   0.0000 1.2261 -0.6247
F5 -1.2261 0.0000 -0.6247   0.0000 -1.2261 -0.6247
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6943 1.6943 1.5896 1.5896
F2 1.6943 3.3820 2.2766 2.2766
F3 1.6943 3.3820 2.2766 2.2766
F4 1.5896 2.2766 2.2766 2.4523
F5 1.5896 2.2766 2.2766 2.4523
Maximum atom distance is 3.3820Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 172.815 F2 S1 F4 87.715
F2 S1 F5 87.715 F3 S1 F4 87.715
F3 S1 F5 87.715 F4 S1 F5 100.953

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.