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Geometry for S2F10 (disulphur decafluoride) 1A1 D4D

1910171554
InChI=1S/F10S2/c1-11(2,3,4,5)12(6,7,8,9)10 INChIKey=

B3LYP/CEP-31G*


Point group is D4d
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 1.1896   1.1896 0.0000 0.0000
S2 0.0000 0.0000 -1.1896   -1.1896 0.0000 0.0000
F3 0.0000 1.6312 1.1931   1.1931 1.6312 0.0000
F4 -1.6312 0.0000 1.1931   1.1931 0.0000 -1.6312
F5 0.0000 -1.6312 1.1931   1.1931 -1.6312 0.0000
F6 1.6312 0.0000 1.1931   1.1931 0.0000 1.6312
F7 0.0000 0.0000 2.8001   2.8001 0.0000 0.0000
F8 1.1534 1.1534 -1.1931   -1.1931 1.1534 1.1534
F9 1.1534 -1.1534 -1.1931   -1.1931 -1.1534 1.1534
F10 -1.1534 -1.1534 -1.1931   -1.1931 -1.1534 -1.1534
F11 -1.1534 1.1534 -1.1931   -1.1931 1.1534 -1.1534
F12 0.0000 0.0000 -2.8001   -2.8001 0.0000 0.0000
Atom - Atom Distances (Å)
  S1 S2 F3 F4 F5 F6 F7 F8 F9 F10 F11 F12
S1 2.3791 1.6312 1.6312 1.6312 1.6312 1.6106 2.8875 2.8875 2.8875 2.8875 3.9897
S2 2.3791 2.8875 2.8875 2.8875 2.8875 3.9897 1.6312 1.6312 1.6312 1.6312 1.6106
F3 1.6312 2.8875 2.3069 3.2624 2.3069 2.2898 2.6930 3.8442 3.8442 2.6930 4.3135
F4 1.6312 2.8875 2.3069 2.3069 3.2624 2.2898 3.8442 3.8442 2.6930 2.6930 4.3135
F5 1.6312 2.8875 3.2624 2.3069 2.3069 2.2898 3.8442 2.6930 2.6930 3.8442 4.3135
F6 1.6312 2.8875 2.3069 3.2624 2.3069 2.2898 2.6930 2.6930 3.8442 3.8442 4.3135
F7 1.6106 3.9897 2.2898 2.2898 2.2898 2.2898 4.3135 4.3135 4.3135 4.3135 5.6002
F8 2.8875 1.6312 2.6930 3.8442 3.8442 2.6930 4.3135 2.3069 3.2624 2.3069 2.2898
F9 2.8875 1.6312 3.8442 3.8442 2.6930 2.6930 4.3135 2.3069 2.3069 3.2624 2.2898
F10 2.8875 1.6312 3.8442 2.6930 2.6930 3.8442 4.3135 3.2624 2.3069 2.3069 2.2898
F11 2.8875 1.6312 2.6930 2.6930 3.8442 3.8442 4.3135 2.3069 3.2624 2.3069 2.2898
F12 3.9897 1.6106 4.3135 4.3135 4.3135 4.3135 5.6002 2.2898 2.2898 2.2898 2.2898
Maximum atom distance is 5.6002Å between atoms F7 and F12.
picture of disulphur decafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 F8 90.124 S1 S2 F9 90.124
S1 S2 F10 90.124 S1 S2 F11 90.124
S1 S2 F12 180.000 S2 S1 F3 90.124
S2 S1 F4 90.124 S2 S1 F5 90.124
S2 S1 F6 90.124 S2 S1 F7 180.000
F3 S1 F4 90.000 F3 S1 F5 179.753
F3 S1 F6 90.000 F3 S1 F7 89.876
F4 S1 F5 90.000 F4 S1 F6 179.753
F4 S1 F7 89.876 F5 S1 F6 90.000
F5 S1 F7 89.876 F6 S1 F7 89.876
F8 S2 F9 90.000 F8 S2 F10 179.753
F8 S2 F11 90.000 F8 S2 F12 89.876
F9 S2 F10 90.000 F9 S2 F11 179.753
F9 S2 F12 89.876 F10 S2 F11 90.000
F10 S2 F12 89.876 F11 S2 F12 89.876

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.