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Geometry for N(SiH3)3 (trisilylamine) 1A' C3H

1910171554
InChI=1S/H9NSi3/c2-1(3)4/h2-4H3 INChIKey=

MP3=FULL/6-311G*


Point group is C3h
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
N1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
Si2 0.0000 1.7437 0.0000   0.0390 -1.7432 0.0000
Si3 -1.5101 -0.8718 0.0000   1.4902 0.9054 0.0000
Si4 1.5101 -0.8718 0.0000   -1.5292 0.8378 0.0000
H5 -1.4173 2.1899 0.0000   1.4659 -2.1577 0.0000
H6 -1.1879 -2.3224 0.0000   1.1357 2.3483 0.0000
H7 2.6052 0.1324 0.0000   -2.6015 -0.1907 0.0000
H8 0.6810 2.2902 1.2014   -0.6296 -2.3048 1.2014
H9 0.6810 2.2902 -1.2014   -0.6296 -2.3048 -1.2014
H10 -2.3239 -0.5553 1.2014   2.3109 0.6071 1.2014
H11 -2.3239 -0.5553 -1.2014   2.3109 0.6071 -1.2014
H12 1.6428 -1.7349 1.2014   -1.6812 1.6977 1.2014
H13 1.6428 -1.7349 -1.2014   -1.6812 1.6977 -1.2014
Atom - Atom Distances (Å)
  N1 Si2 Si3 Si4 H5 H6 H7 H8 H9 H10 H11 H12 H13
N1 1.7437 1.7437 1.7437 2.6085 2.6085 2.6085 2.6744 2.6744 2.6744 2.6744 2.6744 2.6744
Si2 1.7437 3.0201 3.0201 1.4859 4.2360 3.0632 1.4852 1.4852 3.4827 3.4827 4.0302 4.0302
Si3 1.7437 3.0201 3.0201 3.0632 1.4859 4.2360 4.0302 4.0302 1.4852 1.4852 3.4827 3.4827
Si4 1.7437 3.0201 3.0201 4.2360 3.0632 1.4859 3.4827 3.4827 4.0302 4.0302 1.4852 1.4852
H5 2.6085 1.4859 3.0632 4.2360 4.5181 4.5181 2.4200 2.4200 3.1308 3.1308 5.1197 5.1197
H6 2.6085 4.2360 1.4859 3.0632 4.5181 4.5181 5.1197 5.1197 2.4200 2.4200 3.1308 3.1308
H7 2.6085 3.0632 4.2360 1.4859 4.5181 4.5181 3.1308 3.1308 5.1197 5.1197 2.4200 2.4200
H8 2.6744 1.4852 4.0302 3.4827 2.4200 5.1197 3.1308 2.4029 4.1384 4.7854 4.1384 4.7854
H9 2.6744 1.4852 4.0302 3.4827 2.4200 5.1197 3.1308 2.4029 4.7854 4.1384 4.7854 4.1384
H10 2.6744 3.4827 1.4852 4.0302 3.1308 2.4200 5.1197 4.1384 4.7854 2.4029 4.1384 4.7854
H11 2.6744 3.4827 1.4852 4.0302 3.1308 2.4200 5.1197 4.7854 4.1384 2.4029 4.7854 4.1384
H12 2.6744 4.0302 3.4827 1.4852 5.1197 3.1308 2.4200 4.1384 4.7854 4.1384 4.7854 2.4029
H13 2.6744 4.0302 3.4827 1.4852 5.1197 3.1308 2.4200 4.7854 4.1384 4.7854 4.1384 2.4029
Maximum atom distance is 5.1197Å between atoms H5 and H12.
picture of trisilylamine
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Si2 N1 Si3 120.000 Si2 N1 Si4 120.000
Si3 N1 Si4 120.000
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 Si2 H5 107.478 N1 Si2 H8 111.591
N1 Si2 H9 111.591 N1 Si3 H6 107.478
N1 Si3 H10 111.591 N1 Si3 H11 111.591
N1 Si4 H7 107.478 N1 Si4 H12 111.591
N1 Si4 H13 111.591 H5 Si2 H8 109.077
H5 Si2 H9 109.077 H6 Si3 H10 109.077
H6 Si3 H11 109.077 H7 Si4 H12 109.077
H7 Si4 H13 109.077 H8 Si2 H9 107.980
H10 Si3 H11 107.980 H12 Si4 H13 107.980

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.