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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

QCISD/6-31G**


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.2111   0.0000 0.0000 0.2111
F2 0.0000 0.0000 -1.3646   0.0000 0.0000 -1.3646
F3 0.0000 1.6257 0.2473   1.6257 0.0000 0.2473
F4 -1.6257 0.0000 0.2473   0.0000 -1.6257 0.2473
F5 0.0000 -1.6257 0.2473   -1.6257 0.0000 0.2473
F6 1.6257 0.0000 0.2473   0.0000 1.6257 0.2473
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.5757 1.6261 1.6261 1.6261 1.6261
F2 1.5757 2.2893 2.2893 2.2893 2.2893
F3 1.6261 2.2893 2.2991 3.2514 2.2991
F4 1.6261 2.2893 2.2991 2.2991 3.2514
F5 1.6261 2.2893 3.2514 2.2991 2.2991
F6 1.6261 2.2893 2.2991 3.2514 2.2991
Maximum atom distance is 3.2514Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 91.277 F2 S1 F4 91.277
F2 S1 F5 91.277 F2 S1 F6 91.277
F3 S1 F4 89.972 F3 S1 F5 177.447
F3 S1 F6 89.972 F4 S1 F5 89.972
F4 S1 F6 177.447 F5 S1 F6 89.972

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.