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Geometry for CH3MgBr (Methyl Magnesium Bromide) 1A1 C3V

1910171554
InChI=1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1 INChIKey=

PBE1PBE/TZVP


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
C1 0.0000 0.0000 -3.1997   -3.1997 0.0000 0.0000
Mg2 0.0000 0.0000 -1.1233   -1.1233 0.0000 0.0000
Br3 0.0000 0.0000 1.2422   1.2422 0.0000 0.0000
H4 0.0000 1.0178 -3.6001   -3.6001 0.3574 0.9530
H5 0.8814 -0.5089 -3.6001   -3.6001 0.6466 -0.7860
H6 -0.8814 -0.5089 -3.6001   -3.6001 -1.0040 -0.1670
Atom - Atom Distances (Å)
  C1 Mg2 Br3 H4 H5 H6
C1 2.0765 4.4420 1.0937 1.0937 1.0937
Mg2 2.0765 2.3655 2.6777 2.6777 2.6777
Br3 4.4420 2.3655 4.9481 4.9481 4.9481
H4 1.0937 2.6777 4.9481 1.7629 1.7629
H5 1.0937 2.6777 4.9481 1.7629 1.7629
H6 1.0937 2.6777 4.9481 1.7629 1.7629
Maximum atom distance is 4.9481Å between atoms Br3 and H5.
picture of Methyl Magnesium Bromide
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C1 Mg2 Br3 180.000
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Mg2 C1 H4 111.471 Mg2 C1 H5 111.471
Mg2 C1 H6 111.471 H4 C1 H5 107.400
H4 C1 H6 107.400 H5 C1 H6 107.400

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.