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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

ROHF/6-31+G**


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.2025   0.0000 0.0000 0.2025
F2 0.0000 0.0000 -1.3369   0.0000 0.0000 -1.3369
F3 0.0000 1.5863 0.2442   1.3694 0.8006 0.2442
F4 -1.5863 0.0000 0.2442   0.8006 -1.3694 0.2442
F5 0.0000 -1.5863 0.2442   -1.3694 -0.8006 0.2442
F6 1.5863 0.0000 0.2442   -0.8006 1.3694 0.2442
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.5394 1.5868 1.5868 1.5868 1.5868
F2 1.5394 2.2397 2.2397 2.2397 2.2397
F3 1.5868 2.2397 2.2433 3.1726 2.2433
F4 1.5868 2.2397 2.2433 2.2433 3.1726
F5 1.5868 2.2397 3.1726 2.2433 2.2433
F6 1.5868 2.2397 2.2433 3.1726 2.2433
Maximum atom distance is 3.1726Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 91.508 F2 S1 F4 91.508
F2 S1 F5 91.508 F2 S1 F6 91.508
F3 S1 F4 89.960 F3 S1 F5 176.984
F3 S1 F6 89.960 F4 S1 F5 89.960
F4 S1 F6 176.984 F5 S1 F6 89.960

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.