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Geometry for PH4 (Phosphoranyl radical) 2A1 C2V

1910171554
InChI=1S/H4P/h1H4 INChIKey=

M06-2X/aug-cc-pVTZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
P1 0.0000 0.0000 0.0823   0.0000 0.0000 0.0823
H2 0.0000 1.5160 0.2032   1.5160 0.0000 0.2032
H3 0.0000 -1.5160 0.2032   -1.5160 0.0000 0.2032
H4 1.0755 0.0000 -0.8204   0.0000 1.0755 -0.8204
H5 -1.0755 0.0000 -0.8204   0.0000 -1.0755 -0.8204
Atom - Atom Distances (Å)
  P1 H2 H3 H4 H5
P1 1.5208 1.5208 1.4041 1.4041
H2 1.5208 3.0319 2.1219 2.1219
H3 1.5208 3.0319 2.1219 2.1219
H4 1.4041 2.1219 2.1219 2.1509
H5 1.4041 2.1219 2.1219 2.1509
Maximum atom distance is 3.0319Å between atoms H2 and H3.
picture of Phosphoranyl radical
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
H2 P1 H3 170.877 H2 P1 H4 92.931
H2 P1 H5 92.931 H3 P1 H4 92.931
H3 P1 H5 92.931 H4 P1 H5 99.982

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.