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Geometry for Si3H8 (trisilane) 1A1 C2V

1910171554
InChI=1S/H8Si3/c1-3-2/h3H2,1-2H3 INChIKey=VEDJZFSRVVQBIL-UHFFFAOYSA-N

CCD/3-21G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.9009   0.9009 0.0000 0.0000
Si2 0.0000 1.9140 -0.4221   -0.4221 0.0000 1.9140
Si3 0.0000 -1.9140 -0.4221   -0.4221 0.0000 -1.9140
H4 1.2069 0.0000 1.7792   1.7792 1.2069 0.0000
H5 -1.2069 0.0000 1.7792   1.7792 -1.2069 0.0000
H6 0.0000 3.1481 0.4124   0.4124 0.0000 3.1481
H7 0.0000 -3.1481 0.4124   0.4124 0.0000 -3.1481
H8 1.2078 1.9256 -1.2944   -1.2944 1.2078 1.9256
H9 -1.2078 1.9256 -1.2944   -1.2944 -1.2078 1.9256
H10 -1.2078 -1.9256 -1.2944   -1.2944 -1.2078 -1.9256
H11 1.2078 -1.9256 -1.2944   -1.2944 1.2078 -1.9256
Atom - Atom Distances (Å)
  Si1 Si2 Si3 H4 H5 H6 H7 H8 H9 H10 H11
Si1 2.3267 2.3267 1.4926 1.4926 3.1858 3.1858 3.1601 3.1601 3.1601 3.1601
Si2 2.3267 3.8279 3.1568 3.1568 1.4898 5.1304 1.4899 1.4899 4.1185 4.1185
Si3 2.3267 3.8279 3.1568 3.1568 5.1304 1.4898 4.1185 4.1185 1.4899 1.4899
H4 1.4926 3.1568 3.1568 2.4138 3.6381 3.6381 3.6270 4.3573 4.3573 3.6270
H5 1.4926 3.1568 3.1568 2.4138 3.6381 3.6381 4.3573 3.6270 3.6270 4.3573
H6 3.1858 1.4898 5.1304 3.6381 3.6381 6.2963 2.4221 2.4221 5.4877 5.4877
H7 3.1858 5.1304 1.4898 3.6381 3.6381 6.2963 5.4877 5.4877 2.4221 2.4221
H8 3.1601 1.4899 4.1185 3.6270 4.3573 2.4221 5.4877 2.4155 4.5461 3.8513
H9 3.1601 1.4899 4.1185 4.3573 3.6270 2.4221 5.4877 2.4155 3.8513 4.5461
H10 3.1601 4.1185 1.4899 4.3573 3.6270 5.4877 2.4221 4.5461 3.8513 2.4155
H11 3.1601 4.1185 1.4899 3.6270 4.3573 5.4877 2.4221 3.8513 4.5461 2.4155
Maximum atom distance is 6.2963Å between atoms H6 and H7.
picture of trisilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S2 S1 S3 110.693
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 H6 111.283 S1 S2 H8 109.838
S1 S2 H9 109.838 S1 S3 H7 111.283
S1 S3 H10 109.838 S1 S3 H11 109.838
S2 S1 H4 109.546 S2 S1 H5 109.546
S3 S1 H4 109.546 S3 S1 H5 109.546
H4 S1 H5 107.913 H6 S2 H8 108.752
H6 S2 H9 108.752 H7 S3 H10 108.752
H7 S3 H11 108.752 H8 S2 H9 108.314
H10 S3 H11 108.314

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.