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Compare Experimental Geometries - experimental data

Species Name
CH3OCl methyl hypochlorite
The following table lists the experimentally determined internal coordinates. Coordinate descriptions starting with "r" are bond lengths, starting with "a" are bond angles, and starting with "d" are dihedral angles. Atom numbers are the numbers on the picture of the molecule below to indicate which atoms are invloved in the bond or angle.
Units: bond lengths are in Å, angles are in degrees.
description Value Reference Comment Atom number
rCH 1.086 1976Hellwege(II/7) out of plane H 3 5   
rCH 1.111 1976Hellwege(II/7) in plane CH 3 4   
rOCl 1.674 1976Hellwege(II/7)   1 2   
rCO 1.389 1976Hellwege(II/7)   1 3   
aHCH 110.5 1976Hellwege(II/7) in plane to out of plane 4 3 5  
aHCH 108.3 1976Hellwege(II/7) out of plane to out of plane 5 3 6  
aCOCl 112.8 1976Hellwege(II/7)   2 1 3  

picture of
1976Hellwege(II/7) Hellwege, KH and AM Hellwege (ed.). Landolt-Bornstein: Group II: Atomic and Molecular Physics Volume 7: Structure Data of Free Polyatomic Molecules. Springer-Verlag. Berlin. 1976.