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Compare Experimental Geometries - experimental data

Species Name
CH3S thiomethoxy
The following table lists the experimentally determined internal coordinates. Coordinate descriptions starting with "r" are bond lengths, starting with "a" are bond angles, and starting with "d" are dihedral angles. Atom numbers are the numbers on the picture of the molecule below to indicate which atoms are invloved in the bond or angle.
Units: bond lengths are in Å, angles are in degrees.
description Value Reference Comment Atom number
rCH 1.090 1986End/Sai:1770   1 3   
rCS 1.791 1986End/Sai:1770   1 2   
aHCS 110.0 1986End/Sai:1770   2 1 3  
aHCH 108.9 1986End/Sai:1770 by symmetry 3 1 4  

picture of
1986End/Sai:1770 Endo, Saito, Hirota, The microwave spectrum of the thiomethoxy radical CH3S, J. Chem. Phys., Vol. 85, # 4, pgs. 1770-1777