CCCBDB listing of experimental data page 2

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Property	Value	Uncertainty	units	Reference
Hfg(298.15K)	-403.00	2.10	kJ mol^-1	JANAF
Hfg(0K)	-402.00	2.10	kJ mol^-1	JANAF
Entropy (298.15K)	290.17		J K^-1 mol^-1	JANAF
Integrated Heat Capacity (0 to 298.15K)	14.02		kJ mol^-1	JANAF
Heat Capacity (298.15K)	62.39		J K^-1 mol^-1	webbook

Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A₁'	471		1951Scr/Lac:386-387				11B
2	A₂"	460
3	E'	956
4	E'	243

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rBCl	1.742		1	2			1976Hellwege(II/7)

Atom	x (Å)	y (Å)
B1	0.0000	0.0000
Cl2	0.0000	1.7421
Cl3	1.5087	-0.8711
Cl4	-1.5087	-0.8711

	B1	Cl2	Cl3	Cl4
B1		1.7421	1.7421	1.7421
Cl2	1.7421		3.0174	3.0174
Cl3	1.7421	3.0174		3.0174
Cl4	1.7421	3.0174	3.0174

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁^'	D_3h	True				0.000	NSRDS-NBS10		D_3h	0	1

squib	reference	DOI
1951Scr/Lac:386-387	RE Scruby, JR Lacher, JD Park "The Infrared Spectrum of Boron Trichloride" J. Chem. Phys. 19, 386 (1951)	10.1063/1.1748228
1976Hellwege(II/7)	Hellwege, KH and AM Hellwege (ed.). Landolt-Bornstein: Group II: Atomic and Molecular Physics Volume 7: Structure Data of Free Polyatomic Molecules. Springer-Verlag. Berlin. 1976.
1998Gus/Rui:163	M Gussoni, R Rui, G Zerbi "Electronic and relaxation contribution to linear molecular polarizability. An analysis of the experimental values" J. Mol. Struct. 447 (1998) 163-215	10.1016/S0022-2860(97)00292-5
JANAF	Chase, M.W., Jr.; Davies, C.A.; Downey, J.R., Jr.; Frurip, D.J.; McDonald, R.A.; Syverud, A.N., JANAF Thermochemical Tables (Third Edition), J. Phys. Chem. Ref. Data,Suppl. 1, 1985, 14, 1.
NSRDS-NBS10	R. D. Nelson Jr., D. R. Lide, A. A. Maryott "Selected Values of electric dipole moments for molecules in the gas phase" NSRDS-NBS10, 1967	10.6028/NBS.NSRDS.10
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

atom1	atom2	atom3	angle		atom1	atom2	atom3	angle
Cl2	B1	Cl3	120.000		Cl2	B1	Cl4	120.000
Cl3	B1	Cl4	120.000

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Experimental data for BCl3 (Borane, trichloro-)

Experimental data for BCl₃ (Borane, trichloro-)