CCCBDB listing of experimental data page 2

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Property	Value	Uncertainty	units	Reference
Hfg(298.15K)	-12.68	0.84	kJ mol^-1	webbook
Hfg(0K)		0.84	kJ mol^-1	webbook
Entropy (298.15K)			J K^-1 mol^-1
Integrated Heat Capacity (0 to 298.15K)			kJ mol^-1

Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A	3133		1967Cla/Dan:371
2	A	3133
3	A	3080
4	A	3057
5	A	3057
6	A	3000
7	A	1670
8	A	1649
9	A	1400
10	A	1387
11	A	1332
12	A	1305
13	A	1178
14	A	1117
15	A	1020
16	A	996
17	A	951
18	A	852
19	A	837
20	A	837
21	A	713
22	A	700
23	A	580
24	A	452
25	A	276
26	A	187
27	A	85

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rCH	1.103		2	6			1992Kuchitsu(II/21)	average
rCC	1.337		2	4			1992Kuchitsu(II/21)	average
rCO	1.389		1	2			1992Kuchitsu(II/21)	average
aCCO	119		1	2	4		1992Kuchitsu(II/21)
aHCC	115		2	4	8		1992Kuchitsu(II/21)	average
dCOCC	167		2	1	3	5	1992Kuchitsu(II/21)

Bond Type	Count
H-C	6
C=C	2
C-O	2

Atom 1	Atom 2
O1	C2
O1	C3
C2	C4
C2	H6
C3	C5
C3	H7
C4	H8
C4	H9
C5	H10
C5	H11

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	C_2v	False							C_2v	1	2
1	2	¹A	C₁	True	0.349	0.662	0.225	0.782	1971Hir/Cur:358	μ = 0.782D ± 0.026D	C₁	3	5

squib	reference	DOI
1967Cla/Dan:371	ADH Clague, A Danti "Molecular Structure and Vibrational Spectra of Divinyl Ether" J. Mol. Spect. 22, 371-382 (1967)	10.1016/0022-2852(67)90184-1
1971Hir/Cur:358	C Hirose, RF Curl Jr, "Microwave Spectrum, Conformation, and Dipole Moment of Divinyl ether" J. Molecular Spectroscopy 38, 358-366 (1971)	10.1016/0022-2852(71)90119-6
1992Kuchitsu(II/21)	Kuchitsu (ed.), Landolt-Bornstein: Group II: Atomic and Molecular Physics Volume 21: Structure Data of Free Polyatomic Molecules. Springer-Verlag, Berlin, 1992.
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for CH2CHOCHCH2 (Vinyl ether)

Experimental data for CH₂CHOCHCH₂ (Vinyl ether)