CCCBDB listing of experimental data page 2

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Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rSiC	1.868	0.001	1	4			1998Kuc
rSiH	1.482	0.001	1	2			1998Kuc
rCH	1.089		5	7			1998Kuc	assumed
rCH	1.089	0.003	5	7			1998Kuc
aCSiC	110.93	0.07	4	1	5		1998Kuc
aCSiH	109.5	0.03	2	1	5		1998Kuc
aHSiH	107.83	0.08	2	1	3		1998Kuc
aHCSi	110.85	0.4	1	4	6		1998Kuc
aHCSi	111.07	0.23	1	5	10		1998Kuc
aHCH	107.78	0.57	7	5	10		1998Kuc
aHCH	108.08	0.65	10	5	11		1998Kuc

Bond Type	Count
C-Si	2
H-Si	2
H-C	6

Atom 1	Atom 2
Si1	H2
Si1	H3
Si1	C4
Si1	C5
C4	H6
C4	H8
C4	H9
C5	H7
C5	H10
C5	H11

State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	C_2v	True				0.750	NSRDS-NBS10	MW	C_2v	1	2

State	Config	State description	Conf description	Exp. min.	Quadrupole (D Å)			Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	xx	yy	zz	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	C_2v	True						C_2v	1	2

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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squib	reference	DOI
1998Kuc	K Kuchitsu(ed) "Structure of Free Polyatomic Molecules - Basic Data" Springer, Berlin, 1998	10.1007/978-3-642-45748-7
NSRDS-NBS10	R. D. Nelson Jr., D. R. Lide, A. A. Maryott "Selected Values of electric dipole moments for molecules in the gas phase" NSRDS-NBS10, 1967	10.6028/NBS.NSRDS.10
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for SiH2(CH3)2 (dimethylsilane)

Experimental data for SiH₂(CH₃)₂ (dimethylsilane)