CCCBDB listing of experimental data page 2

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Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A₁	235		webbook
2	E	79
3	T₂	327
4	T₂	112

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rGeBr	2.272	0.001	1	2			1975Sou/Wie:442-444	ED r0

Atom	x (Å)	y (Å)	z (Å)
Ge1	0.0000	0.0000	0.0000
Br2	1.3117	1.3117	1.3117
Br3	-1.3117	-1.3117	1.3117
Br4	-1.3117	1.3117	-1.3117
Br5	1.3117	-1.3117	-1.3117

	Ge1	Br2	Br3	Br4	Br5
Ge1		2.2720	2.2720	2.2720	2.2720
Br2	2.2720		3.7102	3.7102	3.7102
Br3	2.2720	3.7102		3.7102	3.7102
Br4	2.2720	3.7102	3.7102		3.7102
Br5	2.2720	3.7102	3.7102	3.7102

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
Br2	Ge1	Br3	109.471	Br2	Ge1	Br4	109.471
Br2	Ge1	Br5	109.471	Br3	Ge1	Br4	109.471
Br3	Ge1	Br5	109.471	Br4	Ge1	Br5	109.471

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	T_d	True							T_d	0	0

squib	reference	DOI
1975Sou/Wie:442-444	GGB Souza, JD Wieser "A Reinvestigation of the structure of GeBr4 by Electron Diffraction" J. Mol. Struct. 25 (1975) 442-444	10.1016/0022-2860(75)85022-8
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for GeBr4 (Germanium tetrabromide)

Experimental data for GeBr₄ (Germanium tetrabromide)