CCCBDB listing of experimental data page 2

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Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A'	1976	2011	webbook				fund from webbook	SiH str
2	A'	772	775	2001Hos/Ndi:5485-5491				equil from Hos/Ndi	bend
3	A'	413	414						SiBr stretch

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rSiH	1.518	0.001	1	3			1996Har/Har:10189-10200
rSiBr	2.237	0.001	1	2			1996Har/Har:10189-10200
aHSiBr	93.4	0.3	2	1	3		1996Har/Har:10189-10200

Atom	x (Å)	y (Å)
Si1	0.0303	1.5641
Br2	0.0303	-0.6729
H3	-1.4850	1.6541

	Si1	Br2	H3
Si1		2.2370	1.5180
Br2	2.2370		2.7769
H3	1.5180	2.7769

Bond Type	Count
Si-Br	1
H-Si	1

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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You are here: Experimental > One molecule all properties

State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A^'	C_s	True							C_s	2	3

squib	reference	DOI
1996Har/Har:10189-10200	H Harjanto, WW Harper, DJ Clouthier "Resolution of anomalies in the geometry and vibrational frequencies of monobromosilylene (HSiBr) by pulsed discharge jet spectroscopy" J. Chem. Phys. 105, 10189 (1996)	10.1063/1.472962
2001Hos/Ndi:5485-5491	DA Hostutler, N Ndiege, DJ Clouthier "Emission spectroscopy, harmonic vibrational frequencies, and improved ground state structures of jet-cooled monochloro- and monobromosilylene HSiCl and HBSir"J. Chem. Phys. 115, 5485 (201)	10.1063/1.1397795
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for HSiBr (monobromosilylene)