CCCBDB listing of experimental data page 2

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Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A₁	2120		webbook
2	A₁	848
3	A₁	422
4	E	2129
5	E	874
6	E	602

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rGeCl	2.145	0.000	1	2			1990Dem/Wlo:322-339	re
rGeH	1.516	0.001	1	3			1990Dem/Wlo:322-339	re
aHGeCl	107.107	0.078	2	1	3		1990Dem/Wlo:322-339

Atom	x (Å)	y (Å)	z (Å)
Ge1	0.0000	0.0000	-0.6581
Cl2	0.0000	0.0000	1.4866
H3	0.0000	1.4485	-1.1040
H4	1.2545	-0.7243	-1.1040
H5	-1.2545	-0.7243	-1.1040

	Ge1	Cl2	H3	H4	H5
Ge1		2.1447	1.5156	1.5156	1.5156
Cl2	2.1447		2.9681	2.9681	2.9681
H3	1.5156	2.9681		2.5089	2.5089
H4	1.5156	2.9681	2.5089		2.5089
H5	1.5156	2.9681	2.5089	2.5089

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
Cl2	Ge1	H3	107.110	Cl2	Ge1	H4	107.110
Cl2	Ge1	H5	107.110	H3	Ge1	H4	111.726
H3	Ge1	H5	111.726	H4	Ge1	H5	111.726

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	C_3v	True			2.130	2.130	1949Dai/May:136-137	MW μ₀	C_3v	1	1

squib	reference	DOI
1990Dem/Wlo:322-339	J Demaison, G Wlodarczak, J Burie, H Bürger "The Rotational Spectrum of Germyl Chloride: Determination and Comparison of the Substitution, Double Substitution, and Equilibrium Structures" J. MOL. SPECT. 140, 322-339 (1990)	10.1016/0022-2852(90)90145-G
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

Bond Type	Count
Cl-Ge	1
H-Ge	3

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Experimental data for GeH3Cl (monochlorogermane)

Experimental data for GeH₃Cl (monochlorogermane)