CCCBDB listing of experimental data page 2

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Property	Value	Uncertainty	units	Reference	Comment
Hfg(298.15K)	-107.03	0.88	kJ mol^-1	1972Joh/Mal:879-891
Hfg(0K)		0.88	kJ mol^-1	1972Joh/Mal:879-891

Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	Σ_g	517		webbook					XeF₂ s-stretch
2	Σ_u	560							XeF₂ a-stretch
3	Π_u	213							bend

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rFXe	1.974	0.000	1	2			1993Bur/Ma:536-539	re
aFXeF	180		2	1	3			from symmetry

Atom	x (Å)	y (Å)	z (Å)
Xe1	0.0000	0.0000	0.0000
F2	0.0000	0.0000	1.9744
F3	0.0000	0.0000	-1.9744

	Xe1	F2	F3
Xe1		1.9744	1.9744
F2	1.9744		3.9487
F3	1.9744	3.9487

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹Σ_G	D_∞h	True							D_∞h	0	1

squib	reference	DOI
1972Joh/Mal:879-891	GK Johnson, JG Malm, WN Hubbard "The enthalpies of formation of XeF6(c), XeF4(c), XeF2(c), and PF3(g)" J. Chem. Thermo. 4 1976, 879-891	10.1016/0021-9614(72)90010-9
1993Bur/Ma:536-539	H Burger, S Ma "The Ground State and Equilibrium Structure of XeF2" J. Mol. Spec. 157, 536-539 (1993)	10.1006/jmsp.1993.1043
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for XeF2 (Xenon difluoride)

Experimental data for XeF₂ (Xenon difluoride)