CCCBDB listing of experimental data page 2

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Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A₁	692		webbook				nu1 and nu3 switched in original (1968Has/Hau:4492)
2	A₁	263		1968Has/Hau:4492
3	B₂	663		2006Ant/Bor:4900				nu1 and nu3 switched in original (1968Has/Hau:4492)

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rGeCl	1.732	0.001	1	2			1971Tak/Cur:464-475
aFGeF	97.17		2	1	3		1971Tak/Cur:464-475

Atom	y (Å)	z (Å)
Ge1	0.0000	0.4125
F2	1.2989	-0.7333
F3	-1.2989	-0.7333

	Ge1	F2	F3
Ge1		1.7321	1.7321
F2	1.7321		2.5979
F3	1.7321	2.5979

Atom 1	Atom 2
Ge1	F2
Ge1	F3

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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You are here: Experimental > One molecule all properties

State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	C_2v	True	0.000	0.000	2.610	2.610	NISTtriatomic	MW μ₀ ± 0.02	C_2v	1	2

squib	reference	DOI
1968Has/Hau:4492	JW Hastie, R Hauge, JL Margrave " Infrared Vibrational Properties of GeF2" J. Phys. Chem., 1968, 72 (13), pp 4492–4496	10.1021/j100859a020
1971Tak/Cur:464-475	H Takeo, RF Curl Jr, PW Wilson "Microwave Spectrum of GeF2" J. Mol. Spect. 38, 464-475 (1971)	10.1016/0022-2852(71)90072-5
2006Ant/Bor:4900	P Antoniotti, S Borocci, N Bronzolino, M Giordani, F Grandinetti "Cationic Germanium Fluorides: A Theoretical Investigation on the Structure, Stability, and Thermochemistry of GeFn/GeFn+ (n=1-3)" J. Phys. Chem. A 2006, 110, 4900-4905	10.1021/jp057064m
NISTtriatomic	NIST Triatomic Spectral Database (http://www.physics.nist.gov/PhysRefData/MolSpec/Triatomic/index.html)	10.18434/T4DW2S
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for GeF2 (Germanium difluoride)

Experimental data for GeF₂ (Germanium difluoride)