CCCBDB listing of experimental data page 2

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Property	Value	Uncertainty	units	Reference
Hfg(298.15K)	156.46	16.70	kJ mol^-1	JANAF
Hfg(0K)	155.64	16.70	kJ mol^-1	JANAF
Entropy (298.15K)	237.32	2.50	J K^-1 mol^-1	JANAF
Integrated Heat Capacity (0 to 298.15K)	9.82		kJ mol^-1	JANAF
Heat Capacity (298.15K)	37.67		J K^-1 mol^-1	webbook

Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	Σ	577		2005Yan/Bog:184304

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rSCl	1.975		1	2			1986Yam/But:108	re value

Atom	x (Å)	y (Å)	z (Å)
S1	0.0000	0.0000	0.0000
Cl2	0.0000	0.0000	1.9753

	S1	Cl2
S1		1.9753
Cl2	1.9753

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	²Π	C_∞v	True							C_∞v	1	1

squib	reference	DOI
1986Yam/But:108	Yamada, C.; Butler, J.; Kentarou, K.; Kanamori, H.; Hirota, E. "Infrared Diode Laser Spectroscopy of the SCl Radical." Journal of Molecular Spectroscopy. 116, 108-111 (1986)	10.1016/0022-2852(86)90256-0
1995How/Ash:773	JD Howe, MNR Ashfold, RA Morgan, CM Western, WJ Buma, JB Milan, CA deLange "Observation of the SCl Radical by Resonance-enhanced Multiphoton Ionisation Spectroscopy" J. Chem. Soc. Faraday Trans. 1995, 91(5), 773-780	10.1039/FT9959100773
2005Yan/Bog:184304	X Yang, JE Boggs "Extensive ab initio study of the electronic state of SCl including spin-orbit coupling" J. Chem. Phys. 123, 184304 (2005)	10.1063/1.2107587
JANAF	Chase, M.W., Jr.; Davies, C.A.; Downey, J.R., Jr.; Frurip, D.J.; McDonald, R.A.; Syverud, A.N., JANAF Thermochemical Tables (Third Edition), J. Phys. Chem. Ref. Data,Suppl. 1, 1985, 14, 1.
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for SCl- (sulfur monochloride anion)

Experimental data for SCl^- (sulfur monochloride anion)