CCCBDB listing of experimental data page 2

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Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	Σ	716	726	NISTdiatomic

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rOBr	1.718		1	2			NISTdiatomic	re

Atom	x (Å)	y (Å)	z (Å)
Br1	0.0000	0.0000	0.0000
O2	0.0000	0.0000	1.7177

	Br1	O2
Br1		1.7177
O2	1.7177

Energy (cm^-1)	Degeneracy	reference	description
0	2		²Π
967.9831	2	1981McK:43

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	²Π	C_∞v	True			1.610	1.610	1971Byf/Car:271		C_∞v	1	1

squib	reference	DOI
1971Byf/Car:271	CR Byfleet, A Carrington, DK Russell, "Electric dipole moments of open-shell diatomic molceules" Molecular Physics 1971, 20(2), 271-277	10.1080/00268977100100251
1981McK:43	ARW McKellar "Laser Magnetic Resonance Spectrum of BrO (2PI1/2 <- 2PI3/2)" J. Mol. Spect. 86, 43-54 (1981)	10.1016/0022-2852(81)90104-1
2000Dyk/Gam:6262-6274	JM Dyke, SD Gamblin, N Hooper, EPF Lee, A Morris, DKW Mok, FT Chau "A study of the BrO and BrO2 radicals with vacuum ultraviolet photoelectron spectroscopy" J. Chem. Phys. 112, 6262 (2000)	10.1063/1.481271
NISTdiatomic	NIST Diatomic Spectral Database (www.physics.nist.gov/PhysRefData/MolSpec/Diatomic/index.html)	10.18434/T4T59X
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for BrO+ (Bromine monoxide cation)

Experimental data for BrO⁺ (Bromine monoxide cation)