CCCBDB listing of experimental data page 2

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Property	Value	Uncertainty	units	Reference
Hfg(298.15K)		1.00	kJ mol^-1	2005Tar/Mil:2881
Hfg(0K)	226.94	1.00	kJ mol^-1	2005Tar/Mil:2881
Entropy (298.15K)	265.35		J K^-1 mol^-1	JANAF
Integrated Heat Capacity (0 to 298.15K)	11.39		kJ mol^-1	JANAF
Heat Capacity (298.15K)	46.25		J K^-1 mol^-1	JANAF

Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A₁	730		VEEL5					CCl₂ s-str
2	A₁	335		VEEL5					CCl₂ scissors
3	B₂	758		VEEL5					CCl₂ a-str

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rCCl	1.711		1	2			2002Dem/Mar:3282	re
aClCCl	109.22		2	1	3		2002Dem/Mar:3282	equilibrium

Atom	y (Å)	z (Å)
C1	0.0000	0.8424
Cl2	1.3951	-0.1487
Cl3	-1.3951	-0.1487

	C1	Cl2	Cl3
C1		1.7113	1.7113
Cl2	1.7113		2.7902
Cl3	1.7113	2.7902

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Experimental data for CCl2- (dichloromethylene anion)

Experimental data for CCl₂^- (dichloromethylene anion)