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Experimental data for CH2F (fluoromethyl radical)

22 02 02 11 45
Other names
Methyl, fluoro-; Methyl radical, fluoro-;
INChI INChIKey SMILES IUPAC name
InChI=1S/CH2F/c1-2/h1H2 VUWZPRWSIVNGKG-UHFFFAOYSA-N [CH2]F
State Conformation
2A CS
Enthalpy of formation (Hfg), Entropy, Integrated heat capacity (0 K to 298.15 K) (HH), Heat Capacity (Cp)
Property Value Uncertainty units Reference Comment
Hfg(298.15K) enthalpy of formation -30.39 0.50 kJ mol-1 2018Gan/Kal:5993-6006
Hfg(0K) enthalpy of formation   0.50 kJ mol-1 2018Gan/Kal:5993-6006
Information can also be found for this species in the NIST Chemistry Webbook
Vibrational levels (cm-1) vibrations
Mode Number Symmetry Frequency Intensity Comment Description
Fundamental(cm-1) Harmonic(cm-1) Reference (km mol-1) unc. Reference
1 A1 3044   webbook      
3 A1 1170          
4 B1 300          
5 B2 3184          

Calculated vibrational frequencies for CH2F (fluoromethyl radical).
Rotational Constants (cm-1) rotational constants
See section I.F.4 to change rotational constant units
A B C reference comment

Calculated rotational constants for CH2F (fluoromethyl radical).
Product of moments of inertia moments of inertia
amu3Å6   0gm3 cm6
Geometric Data
picture of fluoromethyl radical

Point Group Cs

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