CCCBDB listing of experimental data page 2

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Property	Value	Uncertainty	units	Reference	Comment
Hfg(298.15K)	-30.39	0.50	kJ mol^-1	2018Gan/Kal:5993-6006
Hfg(0K)		0.50	kJ mol^-1	2018Gan/Kal:5993-6006

Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A₁	3044		webbook
3	A₁	1170
4	B₁	300
5	B₂	3184

Bond Type	Count
C-F	1
H-C	2

Atom 1	Atom 2
C1	F2
C1	H3
C1	H4

State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	²A	C_s	True							C_s	2	3

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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squib	reference	DOI
2018Gan/Kal:5993-6006	Á Ganyecz, M Kállay, J Csontos "High Accuracy Quantum Chemical and Thermochemical Network Data for the Heats of Formation of Fluorinated and Chlorinated Methanes and Ethanes" J. Phys. Chem. A 2018, 122, 5993−6006	10.1021/acs.jpca.8b00614
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for CH2F (fluoromethyl radical)

Experimental data for CH₂F (fluoromethyl radical)