CCCBDB listing of experimental data page 2

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Property	Value	Uncertainty	units	Reference	Comment
Hfg(298.15K)	90.37	2.09	kJ mol^-1	1990Rus/Sch:1865
Hfg(0K)	101.21	2.09	kJ mol^-1	1990Rus/Sch:1865

Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
1	A₁	2106		webbook					sym stretch
2	E	931		webbook					deg. deform
3	T₂	2114		webbook	332.0	7.0	1994Coa/McK:269		deg. stretch
4	T₂	819		webbook	283.0	6.0	1994Coa/McK:269		deg. deform

Atom 1	Atom 2
Ge1	H2
Ge1	H3
Ge1	H4
Ge1	H5

State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	T_d	True				0.000			T_d	0	0

State	Config	State description	Conf description	Exp. min.	Quadrupole (D Å)			Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	xx	yy	zz	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁	T_d	True						T_d	0	0

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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squib	reference	DOI
1990Rus/Sch:1865	B Ruscic, M Schwarz, J Berkowitz "Photoionization studies of GeHn (n=2-4)" J. Chem. Phys. 92(3), 1990, 1865	10.1063/1.458587
1994Coa/McK:269	AM Coats, DC McKean, D Steele "Infrared Intensities of nu3 and nu4 in SiH4, GeH4, and SnH4" J. Mol. Struct. 320(1994) 269-280	10.1016/0022-2860(94)07974-9
2015Tha/Wu:144302	AJ Thakkar, T Wu "How well do static electronic dipole polarizabilities from gas-phase experiments compare with density functional and MP2 computations?" J. Chem. Phys. 143, 144302 (2015)	10.1063/1.4932594
webbook	NIST Chemistry Webbook (http://webbook.nist.gov/chemistry)	10.18434/T4D303

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Experimental data for GeH4 (Germane)

Experimental data for GeH₄ (Germane)