CCCBDB listing of experimental data page 2

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Mode Number	Symmetry	Frequency			Intensity			Comment	Description
Mode Number	Symmetry	Fundamental(cm^-1)	Harmonic(cm^-1)	Reference	(km mol^-1)	unc.	Reference	Comment	Description
2	A₂"	202		1973Hsa/Hau:285
3	E'	745		1973Hsa/Hau:285
4	E'	192		1973Hsa/Hau:285

Description	Value	unc.	Connectivity				Reference	Comment
Description	Value	unc.	Atom 1	Atom 2	Atom 3	Atom 4	Reference	Comment
rFGa	1.725	0.004	1	2			1992Kuchitsu(II/21)

Atom	x (Å)	y (Å)
Ga1	0.0000	0.0000
F2	0.0000	1.7250
F3	1.4939	-0.8625
F4	-1.4939	-0.8625

	Ga1	F2	F3	F4
Ga1		1.7250	1.7250	1.7250
F2	1.7250		2.9878	2.9878
F3	1.7250	2.9878		2.9878
F4	1.7250	2.9878	2.9878

atom1	atom2	atom3	angle		atom1	atom2	atom3	angle
F2	Ga1	F3	120.000		F2	Ga1	F4	120.000
F3	Ga1	F4	120.000

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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State	Config	State description	Conf description	Exp. min.	Dipole (Debye)				Reference	comment	Point Group	Components
State	Config	State description	Conf description	Exp. min.	x	y	z	total	Reference	comment	Point Group	dipole	quadrupole
1	1	¹A₁^'	D_3h	True							D_3h	0	1

squib	reference	DOI
1973Hsa/Hau:285	JW Hastie, RH Hauge, JL Margrave "Infrared Spectra of Matrix-Isolated Species in the Gallium-Fluorine System" J. Fluorine Chemistry 3 (1973/74) 285-291	10.1016/S0022-1139(00)82628-7
1992Kuchitsu(II/21)	Kuchitsu (ed.), Landolt-Bornstein: Group II: Atomic and Molecular Physics Volume 21: Structure Data of Free Polyatomic Molecules. Springer-Verlag, Berlin, 1992.

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Experimental data for GaF3 (Gallium trifluoride)

Experimental data for GaF₃ (Gallium trifluoride)