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Listing of experimental geometry data for SOF4 (Sulfur tetrafluoride oxide)

No experimental rotational constants available.
Calculated rotational constants for SOF4 (Sulfur tetrafluoride oxide).

Point Group C2v

Internal coordinates

(distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Description Value Connectivity Reference Comment
Atom 1 Atom 2 Atom 3 Atom 4
rSO 1.409 1 2 1982Hed/Hed:598
rFS 1.539 1 5 1982Hed/Hed:598 equatorial
rFS 1.596 1 3 1982Hed/Hed:598 axial
aFSF 112.8 5 1 6 1982Hed/Hed:598 eq to eq
aOSF 97.7 2 1 3 1982Hed/Hed:598 axial F
aFSF 85.7 3 1 5 1982Hed/Hed:598 axial to equatorial
aOSF 123.6 2 1 5 1982Hed/Hed:598 equatorial F
picture of Sulfur tetrafluoride oxide

Bond descriptions


Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
Bond Type Count
O=S 1
F-S 4
Atom x (Å) y (Å) z (Å)
S1 0.0000 0.0000 0.1318
O2 0.0000 0.0000 1.5408
F3 0.0000 1.5816 -0.0821
F4 0.0000 -1.5816 -0.0821
F5 1.2819 0.0000 -0.7199
F6 -1.2819 0.0000 -0.7199

Atom - Atom Distances (Å)
  S1 O2 F3 F4 F5 F6
S11.40901.59601.59601.53901.5390
O21.40902.26612.26612.59882.5988
F31.59602.26613.16322.13342.1334
F41.59602.26613.16322.13342.1334
F51.53902.59882.13342.13342.5637
F61.53902.59882.13342.13342.5637

Calculated geometries for SOF4 (Sulfur tetrafluoride oxide).
References
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squib reference DOI
1982Hed/Hed:598 L Hedberg, K Hedberg "THIONYL TETRAFLUORIDE - REANALYSIS OF THE MOLECULAR-STRUCTURE AND RESOLUTION OF THE MULTIPLE MODEL PROBLEM" J. Phys. Chem. 1982, 86, 598-602 10.1021/j100394a004

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