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Listing of experimental geometry data for LiNH2 (lithium amide)

Rotational Constants (cm-1)


See section I.F.4 to change rotational constant units
A B C
13.16134 1.01142 0.93327
Rotational Constants from 2001Gro/She:5489-5494
Calculated rotational constants for LiNH2 (lithium amide).

Point Group C2v

Internal coordinates

(distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Description Value Connectivity Reference Comment
Atom 1 Atom 2 Atom 3 Atom 4
rLiN 1.736 1 2 2001Gro/She:5489-5494 r0
rHN 1.022 2 3 2001Gro/She:5489-5494
aHNH 106.9 3 2 4 2001Gro/She:5489-5494
picture of lithium amide

Bond descriptions


Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
Bond Type Count
Li-N 1
H-N 2
Atom x (Å) y (Å) z (Å)
Li1 0.0000 0.0000 -1.4034
N2 0.0000 0.0000 0.3326
H3 0.0000 0.8210 0.9412
H4 0.0000 -0.8210 0.9412

Atom - Atom Distances (Å)
  Li1 N2 H3 H4
Li11.73602.48422.4842
N21.73601.02201.0220
H32.48421.02201.6420
H42.48421.02201.6420

Calculated geometries for LiNH2 (lithium amide).
References
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squib reference DOI
2001Gro/She:5489-5494 DB Grotjahn, PM Sheridan, I Al Jihad, LM Ziurys "First Synthesis and Structural Determination of a Monomeric, Unsolvated Lithium Amide, LiNH2" J. Am. Chem. Soc. 2001, 123, 5489-5494 10.1021/ja003422h

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