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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For BF3 (Borane, trifluoro-)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ
Moller Plesset perturbation MP2=FULL -0.000559 -0.006892 -0.006892 -0.004504 -0.012878 -0.012878 -0.013977 -0.074042 -0.074042 -0.026634 -0.091237 -0.091237 -0.067170 -0.008540 -0.052491 -0.119901 -0.010457 -0.060313 -0.121885   -0.145681 -0.209348
MP3=FULL         -0.012422   -0.013532                              
MP4=FULL -0.000537 -0.006462 -0.006462 -0.004237 -0.012667 -0.012653 -0.013768 -0.075861 -0.075861 -0.026763 -0.094027 -0.094027 -0.069493 -0.008006 -0.052815 -0.123744 -0.009980 -0.061221 -0.125823   -0.152000 -0.216208
Coupled Cluster CCSD=FULL -0.000523 -0.006345 -0.006345 -0.004106 -0.012434 -0.012434 -0.013535 -0.075483 -0.075483 -0.026601 -0.093363 -0.093363 -0.069156 -0.007867 -0.052408 -0.122797 -0.009820 -0.060824 -0.125013   -0.151487 -0.214865
CCSD(T)=FULL -0.000536 -0.006406 -0.006406 -0.004164 -0.012576 -0.012577 -0.013681 -0.075819 -0.075819 -0.026761 -0.094015 -0.094015 -0.069441 -0.007955 -0.052821 -0.123698 -0.009920 -0.061243 -0.125789 -0.052821 -0.151952 -0.216103
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ